Dense materials based on silicon carbide were obtained by liquid-phase sintering. The oxides MgO, Y 2 O 3 and Al 2 O 3 , corresponding to the composition of yttrium-aluminum garnet, were used as a sintering additive. and a triple eutectic point on the line of spinel garnet binary cuts. The oxides were deposited on the surface of the powder by the SiC method of coprecipitation from a salt solution. The maximum density (& # 961; rel = 99.5 & # 37;) is achieved on SiC materials including 20 & # 37; (mass content) of sintering additives of a three-component oxide mixture at a temperature of 1800 & # 176; С
Cand. tech. Sciences S. N. PEREVISLOV
1 (
e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it. ), Cand. tech. Sciences A.S. LYSENKOV
2 , Cand. tech. D. D. TITOV
3 , M. V. TOMKOVICH
3 , K. A. KIM
2 , M. G. FROLOVA
2 , Dr. sciences Yu. F. KARGIN
2 , IS MELNIKOVA
4
;
1 Institute of Silicate Chemistry named after IV Grebenshchikov RAS (Russia, St. Petersburg)
2 Institute of Metallurgy and Materials Science named after AA Baikov RAS (Russia, Moscow)
3 A.F. Ioffe RAS (Russia, St. Petersburg)
4 State Research Institute of Civil Aviation (Russia, Moscow)
Izhevskyi VA, Genova LA, Bressiani JC, Bressiani AHA Silicon carbide. Structure, properties and processing // Cer? Mica. 2000. V. 46. N 297. R. 4? 13.
Schwetz KA Silicon carbide based hard materials // Handbook of ceramic hard materials. Weinheim: Wiley-VCH, 2000. P. 683? 748.
Can A., Herrmann M., McLachlan DS et al. Densification of liquid phase sintered silicon carbide // J. Eur. Ceram. Soc. 2006. V. 26. N 9.P. 1707? 1713.
Kim YW, Kim JY, Rhee SH, Kim DY Effect of initial particle size on microstructure of liquid-phase sintered? -Silicon carbide // J. Eur. Ceram. Soc. 2000. V. 20. P. 945? 949.
Tachiwaki T., Yoshinaka M., Hirota K. et al. Novel synthesis of Y3Al5O12 (YAG) leading to transparent ceramics // Solid State Communications. 2001. V. 119. N 10? 11, p. 603? 606.
Lee S.-G., Shim W.-H., Kim J.-Y. et al. Effect of sintering-additive composition on fracture toughness of liquid-phase-sintered SiC ceramics // J. Mater. Sci. Lett. 2001. V. 20. P. 143? 146.
Cho, K.-S., Choi H.-J., Lee J.-G., Kim YW R-curve behavior of layered silicon carbide ceramics with surface fine microstructure // J. Mater. Sci. 2001. V. 36. P. 2189? 2193.
Nogales E., Montone A., Cardellini F. et al. Visible cathodoluminescence from mechanically milled germanium // Semic. Sci. Techn. 2002. V. 17. P. 1267? 1271.
Huang Z., Jia DC, Zhou Y., Liu YG A new sintering additive for silicon carbide ceramic // Ceramics International. 2003. V. 29. P. 13? 17.
Hidaka N., Hirata Y., Sameshima S., Sueyoshi H. Hot-pressing and mechanical properties of SiC ceramics with polytitanocarbosilane // Journal of Ceramic Processing and Research. 2004. V. 5. N 4. P. 331? 336.
Guo X.-Zh., Yang H. Sintering and microstructure of silicon carbide ceramic with Y3Al5O12 added by sol-gel method // J. Zhejiang Univ SCI. 2005. V. 6. N 3. P. 213? 218.
Sevastyanov VG, Simonenko EP, Simonenko NP, Kuznetsov NT Synthesis of fine-dispersed yttrium-aluminum garnet Y3Al5O12 via sol-gel technique // 15th European conference on composite materials. Venice, Italy, 24? 28 June 2012. Venice: 2012. V. 4. P. 1? 8.
Simonenko EP, Simonenko NP, Sevastyanov VG, Kuznetsov NT Synthesis of ultrafine yttrium aluminum garnet using sol-gel technology // Russian Journal of Inorganic Chemistry. 2012. V. 57. N 12. P. 1521? 1528.
Yongheng Zh. Surface modification of ceramic powders by complexes of metal ions in aqueous media // J. Mater. Sci. Lett. 2002. V. 21. P. 1723? 1725.
Nien Y.-T., Chen Y.-L., Chen I.-G. et al. Synthesis of nano-scaled yttrium aluminum garnet phosphor by co-precipitation method with HMDS treatment // Mater. Chem. Phys. 2005. V. 93. P. 79? 83.
Perevislov SN, Panteleev IB, Vikhman SV et al. Co-deposition of oxides from a salt solution onto the surface of silicon carbide particles // Refractories and technical ceramics. 2015.? 9, p. 9? 16.
Perevislov SN, Panteleev IB, Shevchik AP, Tomkovich MV Microstructure and mechanical properties of SiC-materials sintered in the liquid phase with the addition of a finely dispersed agent // Refractories and Industrial Ceramics. 2018. V. 58. N 5.P. 577? 582.
Kikkawa, S., Kijimab A., Hirotab K., Yamaguchi O. Soft solution preparation methods in a ZrO2? Al2O3 binary system // Solid State Ionics. 2002. V. 151. P. 359? 364.
Lorca JL, Pastor JY, Poza P. Influence of the Y2O3 content and temperature on the mechanical properties of melt-grown Al2O3? ZrO2 eutectics // J. Am. Ceram. Soc. 2004. V. 87. N 4. P. 633? 639.
Nesmelov DD, Kozhevnikov OA, Ordanyan SS, Perevislov SN Deposition of the eutectic composition Al2O3? ZrO2 (Y2O3) on the surface of SiC particles // Glass and Ceramics. 2017.? 2.S. 9? 14.
? Nesmelov DD, Kozhevnikov OA, Ordan? Yan SS, Perevislov SN Precipitation of the eutectic Al2O3? ZrO2 (Y2O3) on the surface of SiC particles // Glass and Ceram. 2017. V. 74. N 1? 2.P. 43? 47.?
Kim HS, Kim MK, Kang SB et al. Bending strength and crack-healing behavior of Al2O3 / SiC composites ceramics // Mater. Sci. Eng. (A). 2008. V. 483? 484. P. 672? 675.
Nakao W., Ono M., Lee S. et al. Critical crack-healing condition for SiC whisker reinforced alumina under stress // J. Eur. Ceram. Soc. 2005. V. 25. P. 3649? 3655.
Andoa K., Chua M.-Ch., Tsujib K. et al. Crack healing behavior and high-temperature strength of mullite / SiC composite ceramics // J. Eur. Ceram. Soc. 2002. V. 22. P. 1313? 1319.
Nama KW, Kimb MK, Parka SW et al. Crack-healing behavior and bending strength of Si3N4 / SiC composite ceramics by SiO2 colloidal // Mater. Sci. Eng. (A). 2007. V. 471. P. 102? 105.
Park D.-C., Yano T., Iseki T., Urabe K. Effect of nitrate salts as sintering additives during the ball-milling process of silicon nitride powders // J. Am. Ceram. Soc. 2000. V. 83. N 12.P. 2967? 2973.
Akhmetov NS General and inorganic chemistry. 5th ed., Rev. and add. M .: Higher. shk., 2006.743 p.
Perevislov S.N., Chupov V.D., Ordanyan S.S., Tomkovich M.V. Production of high-density silicon carbide materials by liquid-phase sintering in a system of components SiC? Al2O3? Y2O3? MgO // Refractories and technical ceramics. 2011.? 4/5. S. 26? 32.
Castillo-Rodr? Guez M., Munoz A., Dom? Nguez-Rodr? Guez A. Effect of atmosphere and sintering time on the microstructure and mechanical properties at high temperatures of? -SiC sintered with liquid phase Y2O3? Al2O3 / / Journal of the European Ceramic Society. 2006. V. 26. N 12.P. 2397? 2405.
Perevislov SN, Nesmelov DD Properties of composite ceramics based on SiC and Si3N4 with a nanosized component // Glass and Ceramics. 2016.? 7, p. 15? 18.
? Perevislov SN, Nesmelov DD Properties of SiC and Si3N4 based composite ceramic with nanosize component // Glass and Ceram. 2016. V. 73. N 7? 8.P. 249? 252.?
Perevislov SN Mechanism of liquid-phase sintering of silicon carbide and nitride with oxide activating additives // Glass and Ceramics. 2013.? 7, p. 34? 38.
? Perevislov SN Mechanism of liquid-phase sintering of silicon carbide and nitride with oxide activating additives // Glass and Ceram. 2013. V. 70. N 7? 8.P. 265? 268.?
Perevislov SN, Lysenkov AS, Titov DD, Tomkovich MV Hot-pressed ceramic SiC? YAG materials // Inorganic Materials. 2017. V. 53. N 2.P. 220? 225.
The article can be purchased
electronic!
PDF format
700 руб
UDK 666.3?13
Article type:
Science for ceramic production
Make a request