Broadband luminescence in nano-structured glasses

Cand. chem. N.V. Golubev ¹ ( This email address is being protected from spambots. You need JavaScript enabled to view it. ), E. S. Ignatieva ^{1 , R. Lorenzi 2 , Dr. A. Paleari 1, 2 , Dr. chem. Sciences V. N. Sigaev 1 ( This email address is being protected from spambots. You need JavaScript enabled to view it. ); 1 International Laboratory for Glass-Based Functional Materials. P.D.Sarkisov Russian Chemical Technical University named after D. I. Mendeleeva (Russia, Moscow), 2 University of Milan-Bicocca (Italy, Milan)}

Sigaev VN, Stefanovich S. Yu., Champagnon B. et al. Amor-phous nanostructuring in potassium niobium silicate glasses by SANS and SHG: a new mechanism for second-order optical non-linearity of glass. // J. Non-Cryst. Solids. 2002. V. 306. P. 238-248. Teng Y., Sharafudeen K., Zhou Sh., Qui J. Glass-ceramics for photonic devices // Journal of the Ceramic Society of Japan. 2012. V. 120. P. 458 - 466. Beall GH, Pinckney LR Nanophase Glass-Ceramics // J. Am. Ceram. Soc. 1999. V. 82. P. 5 - 16. Suzuki T., Horibuchi K., Ohishi Y. Structural and optical prop-erties of ZnO - Al ₂ O ₃ - SiO ₂ system glass-ceramics containing Ni ²⁺ -doped nanocrystals // Journal of Non-Crystalline Solids. 2005. V. 351. P. 2304-2309. Wu B., Zhou Sh., Qiu J. et al. Transparent Ni2 + -doped MgO - Al ₂ O ₃ - SiO ₂ glass-ceramics with broadband infrared lumines-cence // Chin. Phys. Lett. 2006. V. 23. P. 2778. Zhou S., Jiang N., Dong H. et al. Size-induced crystal field parameter change and tunable infrared luminescence in Ni ²⁺ -doped high-gallium nanocrystals embedded glass ceramics // Nano-technology. 2008. V. 19. P. 015702. Suzuki T., Murugan GS, Ohishi Y. Optical properties of transparent Li ₂ O - Ga ₂ O _{3 < / sub> - SiO 2 glass-ceramics embedding Ni-doped nanocrystals // Appl. Phys. Letters. 2005. V. 86. P. 131903 - 131906. Suzuki T., Arai Y., Ohishi Y. Crystallization processes of Li 2 O - Ga 2 O 3 - SiO 2 - NiO system glasses // J. Non-Cryst. Solids. 2007. V. 353. P. 36 - 43. Suzuki T., Arai Y., Ohishi Y. Quantum efficiencies of near-infrared emission from Ni ²⁺ -doped glass-ceramics // Journal of Luminescence. 2008. V. 128. P. 603-609. Wu B., Ruan J., Ren J. et al. Enhanced broadband near-infrared luminescence in transparent silicate glass ceramics containing Yb ³⁺ ions and Ni ²⁺ -doped LiGa 5 O 8 nanocrystals // Applied Physics Letters 2008. V. 92. P. 041110. Zhou S., Feng G., Wu B. et al. Intense Infrared luminescence in transparent glass-ceramics containing & beta; -Ga 2 O 3 : Ni ²⁺ nanocrystals // J. Phys. Chem. S. 2007. V. 111. P. 7335 - 7338. N. V. Golubev, V. I. Savinkov, E. S. Ignatieva, et al. Nickel-activated gallium-containing glasses luminescent in the near-IR spectral range // Physics and chemistry of glass. 2010. T. 36. S. 835 - 842. Sigaev VN, Golubev NV, Ignat'eva ES et al. Nickel-assisted growth and selective doping of spinel-like gallium oxide nanocrystals in germano-silicate glasses for infrared broadband light emission // Nanotechnology. 2012. V. 23. P. 015708-015715. Mashinsky VM, Karatun NM, Bogatyrev VA et al. Micro-fluorescence Analysis of Nanostructuring Inhomogeneity in Optical Fibers with Embedded Gallium Oxide Nanocrystals // Microsc. Microanal. 2012. V. 18. P. 259 - 265. Sigaev VN, Golubev NV, Ignat'eva ES et al. Native amorphous nanoheterogeneity in gallium germanosilicates as a tool for driving Ga 2 O 3 nanocrystal formation in glass for optical devices // Nanoscale. 2013. V. 5. P. 299. Wu B., Zhou S., Ren J. et al. Enhanced luminescence from transparent Ni ²⁺ -doped MgO - Al 2 O 3 - SiO 2 glass ceramics by Ga 2 O 3 addition // Journal of Physics and Chemistry of Solids. 2008. V. 69. P. 891 - 894. Reznitskiy LA Calorimetry of a solid (structural, magnetic, electronic transformations). Moscow: Moscow State University Publishing House, 1981.184 p. Moncorge R., Thery J., Vivien D. Enhancement of fluorescence from octahedrally coordinated Ni 2 in LaMgAl11O19 materials by Al ³⁺ / Ga ^{3 + ion substitution // Journal of Luminescence. 1989. V. 43. P. 167 - 172. Suzuki T., Murugan GS, Ohishi Y. Spectroscopic properties of a novel near-infrared tunable laser material Ni: MgGa 2 O 4 < / sub> // Journal of Luminescence. 2005. 113. P. 265-270. Wang T., Farvid Sh. S., Abulikemu M., Radovanovic PV Size-tunable phosphorescence in colloidal metastable & gamma; -Ga 2 O 3 nanocrystals // J. Am. Chem. Soc. 2010. V. 132. P. 9250 - 9252. Dubrovo SK, Lileev IS Glassy gallosilicates and their properties // Journal of Applied Chemistry. 1960. XXXIII. Pp . 1471-1476. Campbell JH, Suratwala TI, Thorsness CB et al. Continuous melting of phosphate laser glasses // Journal of Non-Crystalline Solids. 2000.263 & 264. P. 342 - 357. Murphy MK, Emery K. Properties and structure of glasses in the system M 2 O - Ga 2 O 3 - GeO 2 (M = Li, Na, K) // Physics and chemistry of glasses. 1967. 8. P. 26-29 Tanaka K., Mukai T., Ishiham Ts. et al. Preparation and optical properties of transparent glass-ceramics containing cobalt (II) ions // J. Am. Ceram. Soc. 1993. V. 76. P. 2839 - 2845. Andreev NS, Mazurin OV Poray-Koshits EA et al. Phenomena of liquation in glasses. L .: Nauka, 1974.220 p. Golubkov V.V., Dymshits O.S., Zhilin A.A. Influence of nickel oxide additives on phase decomposition processes in lithium aluminosilicate glasses containing titanium dioxide // Glass Physics and Chemistry. 1984. V. 10. P. 155 - 161. Golubkov V. V., Dymshits O.S., Zhilin A. A. et al. On phase separation and crystallization of glasses of the MgO - Al 2 system O 3 - SiO 2 - TiO 2 // Glass Physics and Chemistry. 2003. T. 29. P. 359 - 377. Kuleshova NV, Shcherbitsky VG, Mikhailov VP et al. Spectroscopy and excited-state absorption of Ni 2+ -doped MgA 12 O 4 // Journal of Luminescence. 1997. V. 71. P. 265-268.}}