The influence of underglaze paints in the form of solutions of cobalt and nickel salts on the formation of the structure of a porcelain article, especially in the zone of contact between porcelain and glaze, has been established. In this zone, salts change the character and size of crystalline neoplasms. Cobalt ions form compounds that are more soluble in the glass phase of porcelain and glaze than nickel ions, as evidenced by the color of the glassy layer of the glaze. With increasing salt content, a crystalline paint layer forms on both sides of the product.
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