Steklo i Keramika (Glass and Ceramics). Monthly scientific, technical and industrial journal

 

ISSN 0131-9582 (Online)

  • Continuous numbering: 1115
  • Pages: 19-23
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The effect of Nd 2 O 3 (0.1 - 3.0 & # 37;, molar content) oxide additives on the synthesis conditions, crystallization and spectral properties of heat-resistant sitall of the Li system was studied 2 O & ndash; Al 2 O 3 & ndash; SiO 2 (LAS). Introducing it to 1 & # 37; molar content of Nd 2 O 3 does not affect the crystallization properties and precipitation of the main crystalline phase of & # 946; -eucryptite-like solid solutions Li x Al x Si l & ndash; x O 2 , while an increase in the molar content of Nd 2 O 3 to 3 & # 37; significantly changes the character of crystallization of LAS glass. The results obtained show that an optical sitall with a near-zero LTEC value, activated by neodymium ions up to the N N d 3 + & # 8776; 4 & middot; 10 2 0 cm & ndash; 3 , can be considered as a basis for creating new light-emitting thermostable optical media
Glass-Ceramics / by PW McMillan2nd ed. New York: Academic Press, 1979. M?ller G. Structure, composition, stability, and thermal expansion of high-quartz and keatite-type alumino-silicates // Low Thermal Expansion Glass Ceramics. Berlin: Springer, 1995. P. 13? 24. Sigaev VN, Lipat'ev AS, Fedotov SS, et al. Femtosecond laser modification of transparent lithium-aluminosilicate glass and initial glass containing antimony // Glass and Ceramics. 2019.? 10.S. 9? 13. [Sigaev VN, Lipat? Ev AS, Fedotov SS et al. Femtosecond Laser Modification of Antimony-Containing Lithium-Aluminum-Silicate Glass and Transparent Sitall Obtained from It // Glass Ceram. 2019. V. 76, No. 9-10. P. 370? 373.] Zanotto E. A bright future for glass-ceramics // Am. Ceram. Soc. Bull. 2010. V. 89. P. 19? 27. Pat. RF 2 569 703 C1 IPC C03C 10/12. Method of obtaining optical glass / V. N. Sigaev, V. I. Savinkov, E. E. Stroganova, A. N. Ignatov. Publ. 11/27/2015. Sigaev V.N., Savinkov V.I., Shakhgildyan G. Yu., Et al. On the possibility of precision control of the temperature coefficient of linear expansion of transparent lithium aluminum silicate sitalls near zero values ??// Glass and Ceramics. 2019.? 12, p. 11? 16. [Sigaev VN, Savinkov VI, Shakhgil'dyyan GY et al. On the Possibility of Precision Control of the Linear Thermal Expansion Coefficient of Transparent Lithium-Aluminum- Silicate Sitals Near Zero Values ??// Glass Ceram. 2019. V. 76, No. 11-12. P. 446? 450.] Dmitriuk AV, Karapetian GO, Maksimov LV The phenomenon of activator segregation and its spectroscopic consequences // J. Appl. Spectroc. 1975. V. 22. P. 153? 182. Savinkov VI, Shakhgildyan G. Yu., Naumov AS, et al. Influence of antimony oxide on the crystallization features of lithium-aluminosilicate glasses // Glass and Ceramics. 2019.? 10.S. 30? 34. [Savinkov VI, Shakhgil'dyyan GY, Naumov AS et al. Effect of Antimony Oxide on the Crystallization Particulars of Lithium-Aluminum-Silicate Glasses // Glass Ceram. 2019. V. 76, No. 9-10. P. 387? 390.]

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Savinkov V. I., Naumov A. S., Lotarev S. V., Klimenko N. N., Ig-nat?eva E. S., Sigaev V. N. Thermally Stable Transparent LithiumAluminosilicate Glass-Ceramics Doped with Neodymium Oxide. Steklo i keramika. 2020:93(11):19-23. (in Russ). UDK 666.221.6