Steklo i Keramika (Glass and Ceramics). Monthly scientific, technical and industrial journal

 

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The difference in the mechanism of synthesis of yttrium-aluminum garnet Y 3 Al 5 O 12 (YAG) from a mixture of double yttrium and ammonium carbonate NH 4 Y (CO 3 ) 2 & middot; H 2 O with aluminum and ammonium hydroxycarbonate NH 4 AlCO 3 (OH) 2 and mixtures of hydrated yttrium and aluminum oxides. Calcining a mixture of hydrated oxides leads to the formation of both Y 3 Al 5 O 12 and impurity phases Y 4 Al 2 O 9 and YAlO 3 , while after calcining the mixture of carbonates, a monophase YAG is formed. The difference in the mechanism of YAG synthesis is presumably due to the difference in particle sizes formed after calcination of carbonates and hydrated oxides.
Dr. Tech. Sciences V. A. MATVEEV (This email address is being protected from spambots. You need JavaScript enabled to view it.), K. A. YAKOVLEV (e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.); Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials named after IV Tananaeva - a separate subdivision of the Federal State Budgetary Scientific Institution of the Federal Research Center & # 171; Kola Scientific Center of the Russian Academy of Sciences & # 187; (ICHTREMS KSC RAS) (Russia, Apatity)
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Matveev V. A., Yakovlev K. A. Synthesis of Yttrium-Aluminum Garnet Based on Double Ammonium-Containing Yttrium-Aluminum Carbonate Compounds. Steklo i keramika. 2021:94(2):37-42. (in Russ). UDK 546.05:549.613.4