Organo-inorganic hybrid materials based on inorganic oxofluoride lead-borosilicate glass matrices and a metal complex compound of tris- (8-oxycholate) it-terbium (III) were obtained by the melt method. The spectral-luminescent properties of tris- (8-oxycholate) ytterbium and hybrid materials in the visible and IR regions have been studied at various excitations (377 and 785 nm). It is shown that the intensity of IR luminescence in the initial metal-complex phosphor exceeds the luminescence in the visible region, and in the obtained hybrid materials, on the contrary: the intensity of visible luminescence is significantly higher than the IR luminescence.
K. I. RUNINA, L. V. POPKOVA, A. V. KHOMYAKOV, Cand. chem. RI AVETISOV, Dr. of Chem. Sciences OB PETROVA (This email address is being protected from spambots. You need JavaScript enabled to view it.), Dr. Sciences I. Kh. AVETISOV; Federal State Budgetary Educational Institution of Higher Education & # 171; Russian University of Chemical Technology. D. I. Mendeleev & # 187; (RKhTU named after D.I.Mendeleev) (Moscow, Russia)
Schubert U. Cluster-based inorganic-organic hybrid materials // Chem. Soc. Rev. 2011. V. 40. P. 575? 582.
Lebeau B., Innocenzi P. Hybrid materials for optics and photonics // Chem. Soc. Rev. 2011. V. 40. P. 886? 906.
Parola S., Juli? NL? Pez B., Carlos LD, Sanchez C. Optical Properties of Hybrid Organic-Inorganic Materials and their Applications // Adv. Funct. Mater. 2016.V. 26. P. 6506? 6544.
Liu W., Lustig WP, Lib J. Luminescent inorganic-organic hybrid semiconductor materials for energy-saving lighting applications // Energy Chem. 2019. V. 1, No. 2. P. 100008.
Escribano B. Julia? N-Lo? Pez, J. Planelles-Arago ?, E. Cordoncillo et al. Photonic and nanobiophotonic properties of luminescent lanthanide-doped hybrid organic-inorganic materials // Journal of Materials Chemistry. 2008. V. 18. P. 23? 40.
Cordoncillo E., Escribano P., Guaita FJ et al. Optical Properties of Lanthanide Doped Hybrid Organic-Inorganic Materials // Journal of Sol-Gel Science and Technology. 2002. V. 24. P. 155? 165.
Que W., Hu X. Optical switch and luminescence properties of sol-gel hybrid organic-inorganic materials containing azobenzene groups and doped with neodymium ions // Appl. Phys. B. 2007. V. 88. P. 557? 561.
Runina KI, Mayakova MN, Taydakov IV et al. Luminescent hybrid materials based on metal-organic phosphors in PbF2 powder and PbF2-containing glass matrix // Optical Materials. 2019. V. 88. P. 378? 384.
Petrova O., Taydakov I., Anurova M. et al. New fluorescent hybrid materials based on Eu-complexes in oxyfluoride glass and glass-ceramic matrix // Periodica Polytechnica: Chemical Engineering. 2016. V. 60, No. 3.P. 152? 156.
Taydakov IV, Lobanov AH, Lepnev L.S., Vitukhnovsky A.G. Synthesis and photophysical properties of tris (1,3-bis (1,3-dimethyl-1H-pyrazol-4-yl) propane- 1,3-dionato) (1,10-phenanthroline) neodymium (III) // Coordination chemistry. 2014.Vol. 40,? 1.S. 20? 26.
[Taidakov IV, Lobanov AN, Lepnev LS, Vitukhnovskii AG Neodymium (III) tris (1,3-bis (1,3-dimethyl-1H-pyrazol-4-yl) propane-1,3-dionato) (1 , 10-phenanthroline): Synthesis and photophysical properties // Russian Journal of Coordination Chemistry. 2014. V. 40, No. 1.P. 16? 22.]
Metlina DA, Metlin MT, Ambrozevich SA et al. Bright NIR-luminescent Nd3 + complexes with pyrazole-substituted 1,3-diketones demonstrated an unusual spectral lines branching ratios // Dyes and Pigments. 2020. V. 181. P. 108558
Anurova MO, Runina KI, Khomyakov AV et al. The effect of borate glass matrix on the luminescence properties of organic? Inorganic hybrid materials // Physics and Chemistry of Glasses: European Journal of Glass Science and Technology. Pt B. 2019. V. 60, No. 4. P. 140? 145.
Zhang Q., Yang X., Deng R. et al. Synthesis and Near Infrared Luminescence Properties of a Series of Lanthanide Complexes with POSS Modified Ligands // Molecules. 2019. V. 24, No. 7. P. 1253.
Kassab LRP, Courrol LC, Wetter NU et al. Lead fluoroborate glass doped with ytterbium // Journal of Alloys and Compounds. 2002. V. 344. P. 264? 267.
Najafi E., Amini MM, Mohajerani E. et al. Fabrication of an organic light-emitting diode (OLED) from a two-dimensional lead (II) coordination polymer // Inorganica Chimica Acta. 2013. V. 399. P. 119? 125.
Mei Q., ??Du N., Lu M. Synthesis and Characterization of High Molecular Weight Metaloquinolate-Containing Polymers // Journal of Applied Polymer Science. 2006. V. 99. P. 1945? 1952.
Bharathi DV, Arulmozhichelvan P. Murugakoothan P. Synthesis and characterization of Znq2 and Znq2: CTAB particles for optical applications // Bull. Mater. Sci. 2017. V. 40. P. 1049? 1053.
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