A new luminescent hybrid material based on silica aerogel and a boron-containing coordination compound with 8-hydroxyquinoline has been created, and its physico-chemical and spectral-luminescent characteristics have been studied. A scheme for the synthesis of a hybrid luminescent material has been developed/ The scheme eliminates the need for preliminary expensive synthesis of a high-purity organoelemental boron-containing phosphor. It has been established that aerogel hydrophobization significantly increases the stability of the luminescent characteristics of the hybrid material.
Ekaterina N. Suslova – Ph.D. student, Head of the laboratory, Department of Chemical and Pharmaceutical ENGINEERING, Mendeleev University of Chemical Technology of Russian, Moscow, Russia.E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
Ksenia V. Kazmina – Ph.D. student, Researcher OF THE Youth Laboratory of Functional Materials for Photonics AND ELECTRONICS of the Department of Chemistry and Technology of Crystals, MENDELEEV University of Chemical Technology of Russian, Moscow, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
Krisina I. Runina – Ph.D. student, Researcher of the Youth Laboratory of Functional Materials for Photonics and ELECTRONICS of THE DEPARTMENT OF Chemistry and Technology of Crystals, Mendeleev University of Chemical Technology of Russian, Moscow, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
Danil A. Kunaev – Bachelor, Department of Chemical and Pharmaceutical Engineering, Mendeleev University of Chemical Technology of Russian, Moscow, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
Artem E. Lebedev – Ph.D., Senior Researcher, Department of Chemical and Pharmaceutical Engineering, Mendeleev University of Chemical Technology of Russian, Moscow, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
Olga B. Petrova – Dr., Docent, Professor of The Department of Chemistry and Technology of Crystals, Mendeleev University of Chemical Technology of Russian, Moscow, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
Natalia V. Menshutina – Dr, Professor, Head of the Department of Chemical and Pharmaceutical Engineering, Mendeleev University of Chemical Technology of Russian, Moscow, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
Igor Ch. Avetissov – Dr., Professor, Head of The Department of Chemistry and Technology of Crystals, Mendeleev University of Chemical Technology of Russian, Moscow, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.
1. Mertens R. The Oled Handbook (ed. 2019). A Guide to OLED Technology, Industry and Market., Lulu Press, Inc, 2019. 202 p.
2. Organic Electronics: Materials, Processing, Devices and Applications, Taylor and Francis Group / ed. Franky S. Boca Raton, 2010. 581 p.
3. Chen W. C., Liou P. H., Chen B. J. Optimization Design for the Dot Pattern of Led Light Guide Plate Using Soft Computing // J. Appl. Sci. 2013. V. 13. P. 2378 – 2383.
4. Bando K., Sakano K., Noguchi Y., Shimizu Y. Development of High-bright and Pure-white LED Lamps // J. Light Vis. Environ. 1998. V. 22. P. 2 – 5.
5. Daicho H., Enomoto K., Sawa H., et al. Improved color uniformity in white light-emitting diodes using newly developed phosphors // Opt. Express. 2018. V. 26. P. 24784.
6. Aerogels Handbook / eds. M. A. Aegerter, N. Leventis, M. M. Koebel. New York: Springer, 2011. URL: https://doi.org/10.1007/978-1-4419-7589-8.
7. Koebel M., Rigacci A., Achard P. Aerogel-based thermal superinsulation: an overview // J. Sol-Gel Sci. Technol. 2012. V. 63. P. 315 – 339.
8. Karami D. A. Review of Aerogel Applications in Adsorption and Catalysis // J. Pet. Sci. Technol. 2018. V. 8. P. 3 – 15.
9. Zhai Z., Ren B., Xu Y., et al. Nitrogen self-doped carbon aerogels from chitin for supercapacitors // J. Power Sources. 2021. V. 481. P. 228976.
10. Lovskaya D., Menshutina N., Mochalova M., et al. Chitosan-Based Aerogel Particles as Highly Effective Local Hemostatic Agents. Production Process and In Vivo Evaluations // Polymers (Basel). 2020. V. 12. P. 2055.
11. Wang H., Shao Z., Bacher M., et al. Fluorescent cellulose aerogels containing covalently immobilized (ZnS)x(CuInS2)1?x/ZnS (core/shell) quantum dots // Cellu-lose. 2013. V. 20. P. 3007 – 3024.
12. Xu L., Selin V., Zhuk A., et al. Molecular Weight Dependence of Polymer Chain Mobility within Multilayer Films // ACS Macro Lett. 2013. V. 2. P. 865 – 868.
13. Amlouk A., El Mir L., Kraiem S., et al. Lumines-cence of TiO2:Pr nanoparticles incorporated in silica aerogel // Mater. Sci. Eng. B. 2008. V. 146. P. 74 – 79.
14. Zhang W., Liu Y., Yu H., Dong X. Eu and Tb co-doped porous SiO2 aerogel composite and its luminescent properties // J. Photochem. Photobiol. A Chem. 2019. V. 379. P. 47 – 53.
15. Xu L., Chu Z., Wang H., et al. Electrostatically Assembled Multilayered Films of Biopolymer Enhanced Nanocapsules for on-Demand Drug Release // ACS Appl. Bio Mater. 2019. V. 2. P. 3429 – 3438.
16. Xu L., Wang H., Chu Z., et al. Temperature-Responsive Multilayer Films of Micelle-Based Composites for Controlled Release of a Third-Generation EGFR Inhibitor // ACS Appl. Polym. Mater. 2020. V. 2. P. 741 – 750.
17. Lu Y., Zhuk A., Xu L., et al. Tunable pH and temperature response of weak polyelectrolyte brushes: role of hydrogen bonding and monomer hydrophobicity // Soft Matter. 2013. V. 9. P. 5464.
18. Allison S. W., Baker E. S., Lynch K. J., Sabri F. In vivo X-Ray excited optical luminescence from phosphor-doped aerogel and Sylgard 184 composites // Radiat. Phys. Chem. 2017. V. 135. P. 88 – 93.
19. Solovieva A. B., Kopylov A. S., Savko M. A., et al. Photocatalytic Properties of Tetraphenylporphyrins Immobilized on Calcium Alginate Aerogels // Sci. Rep. 2017. V. 7. P. 12640.
20. Ma Y., Chen X., Bai J., et al. Highly selective fluorescence chemosensor based on carbon-dot-aerogel for detection of aniline gas // Inorg. Chem. Commun. 2019. V. 100. P. 64 – 69.
21. Petrova O., Taydakov I., Anurova M., et al. Luminescent hybrid materials based on an europium organic complex and borate glasses // J. Non. Cryst. Solids. 2015. V. 429. P. 213 – 218.
22. Men’shutina N. V., Katalevich A. M., Smirnova I. Preparation of silica-based aerogels by supercritical drying // Russ. J. Phys. Chem. B. 2014. V. 8. P. 973 – 979.
23. Lebedev A., Suslova E., Runina K., et al. New efficient lighting device. Part 1. Hybrid materials based on inorganic aerogel and metal-organic phosphor // J. Solid State Chem. 2021. V. 302. P. 122358.
24. Avetisov R., Kazmina K., Barkanov A., et al. One-Step Synthesis of High Pure Tris (8-Hydroxyquinoline) Aluminum for Optics and Photonics // Materials. 2022. V. 15, No. 3. P. 734.
25. Zykova M., Runina K., Popkova L., et al. Lumi-nescent properties of organic–inorganic hybrid films fabricated by capillary coating technique // Applied Physics A. 2022. V. 128. P. 240.
26. Gupta R. B., Shim J.-J. Solubility in Supercritical Carbon Dioxide. 1st ed. Boca Raton: CRC Press, 2006. 958 p.
27. Keller P. C., Marks R. L., Rund J. V. Reactions of diborane with aromatic heterocycles–21: Reactions with nitrogen-containing heterocycles related to pyridine // Polyhedron. 1983. V. 2, Is. 7. P. 595 – 602.
28. Durka K., G?owacki I., Luli?ski S., et al. Efficient 8-oxyquinolinato emitters based on a 9,10-dihydro-9,10-diboraanthracene scaffold for applications in optoelectro-nic devices // J. Mater. Chem. C. 2015. V. 3. P. 1354 – 1364.
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