The influence of the structure and properties of acrylate monomers on the rheology and polymerization of suspensions containing partially stabilized zirconium dioxide, a dispersant and a photoinitiator as a ceramic filler is investigated. It has been shown that the use of the DISPERBYK 2013 additive makes it possible to obtain suspensions containing 1,6-hexanediol diacrylate, dipropylene glycol diacrylate and tripropylene glycol diacrylate with a viscosity value below 5 Pa?s at high
(up to 41 vol. %) filling with TZ-3YS-E powder. The possibility of using the obtained suspensions for three-dimensional printing of high-density ceramic products with complex geometry has been established.
Lydia V. Ermakova – intern-researcher – IREA, laboratory assistant-researcher – NRC KI, Moscow, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
Daria E. Kuznetsova – Candidate of Chemical Sciences, senior researcher, National Research Center “Kurchatov Institute”, Moscow, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
Dmitry S. Poplevin – Candidate of Chemical Sciences, senior researcher, National Research Center “Kurchatov Institute”, Moscow, Russia E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.
Valentina G. Smyslova – junior researcher – IREA, laboratory assistant-researcher – NRC KI, Moscow, Russia E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.
Petr V. Karpyuk – Candidate of Chemical Sciences, researcher, National Research Center “Kurchatov Institute”, Moscow, Russia E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.
Petr S. Sokolov – Candidate of Chemical Sciences, senior researcher, National Research Center “Kurchatov Institute”, Moscow, Russia E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.
Georgy A. Dosovitskiy – Candidate of Chemical Sciences, leading researcher, National Research Center “Kurchatov Institute”, Moscow, Russia E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.
Svetlana V. Chizhevskaya – Doctor of Chemical Sciences, professor of Department of Technology of Rare Elements and NanoMaterials Based on them Mendeleev University of Chemical Technology of Russia, Moscow, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
1. Lian Q., Sui W., Wu X., et al. Additive manufactur-ing of ZrO2 ceramic dental bridges by stereolithography // Rapid Prototyping Journal. 2018. V. 24, No. 1. P. 114 – 119. DOI: 10.1108/RPJ-09-2016-0144.
2. Borlaf M., Serra-Capdevila A., Colominas C., Graule T. Development of UV-curable ZrO2 slurries for additive manufacturing (LCM-DLP) technology // Journal of the European Ceramic Society. 2019. V. 39, No. 13. P. 3797 – 3803. DOI: 10.1016/j.jeurceramsoc.2019.05.023.
3. Zhang K., He R., Wang G., et al. Photosensitive ZrO2 suspensions for stereolithography // Ceramics International. 2019. V. 45, No. 9. P. 12189 – 12195. DOI: 10.1016/j.ceramint.2019.03.123.
4. Zhang K., Xie C., Wang G., et al. High solid loading, low viscosity photosensitive Al2O3 slurry for stereolithography based additive manufacturing // Ceramics International. 2019. V. 45, No. 1. P. 203 – 208. DOI: 10.1016/j.ceramint.2018.09.152.
5. Hosta?a J., Schwentenwein M., Toci G., et al. Transparent laser ceramics by stereolithography // Scripta Materialia. 2020. V. 187. P. 194 – 196. DOI: 10.1016/j.scriptamat.2020.06.006.
6. Ji L., Chang W., Cui M., et al. Photopolymeri¬zation kinetics and volume shrinkage of 1, 6-hexanediol diacrylate at different temperature // Journal of Photo-chemistry and Photobiology. A: Chemistry. 2013. V. 252. P. 216 – 221. DOI: 10.1016/j.jphotochem.2012.12.010.
7. Camargo I. L., Erbereli R., Taylor H., et al. 3Y-TZP DLP additive manufacturing: solvent-free slurry development and characterization // Materials Research. 2021. V. 24. P. e20200457. DOI: 10.1590/1980-5373-MR-2020-0457
8. Ma L., Huang B., Wei C., et al. Study on Volume Shrinkage Performance of 3D Printing Materials // Advanced Graphic Communication, Printing and Packaging Technology. 2020. P. 715 – 721. DOI: 10.1007/978-981-15-1864-5_97
9. Technical Data Sheet // DISPERBYK 2013 URL: https://www.byk.com/en/products/additives-by-name/disperbyk-2013 (дата обращения: 06.03.2022)
10. Bonada J., Barcelona P., Casafont M., et al. Analysis of the compression behaviour of reinforced photocurable materials used in additive manufacturing processes based on a mask image projection system // Materials. 2021. V. 14, No. 16. P. 4605. DOI: 10.3390/ma14164605
11. Соколов П. С., Комиссаренко Д. А., Досовицкий Г. А. и др. Реологические свойства суспензий оксида циркония в акрилатных мономерах для использования в 3D-печати // Стекло и керамика. 2018. № 2. С. 18 – 23.[Sokolov P. S., Komissarenko D. A., Dosovitskii G. A., et al. Rheological properties of zirconium oxide suspensions in acrylate monomers for use in 3D printing // Glass Ceram. 2018. V. 75, No. 1-2. P. 55 – 59. DOI: 10.1007/s10717-018-0028-3.]
12. Komissarenko D. A., Sokolov P. S., Evstigneeva A. D., et al. DLP 3D printing of scandia-stabilized zirconia ceramics // Journal of the European Ceramic Society. 2021. V. 41, No. 1. P. 684 – 690. DOI: 10.1016/j.jeurceramsoc.2020. 09.010.
13. Komissarenko D. A., Sokolov P. S., Evstigneeva A. D., et al. Rheological and curing behavior of acry-late-based suspensions for the DLP 3D printing of complex zirconia parts // Materials. 2018. V. 11, No. 12. P. 2350. DOI: 10.3390/ma11122350
14. Preobrazhenskiy I. I., Tikhonov A. A., Evdokimov P. V., et al. DLP printing of hydrogel/calcium phosphate composites for the treatment of bone defects // Open Ceramics. 2021. V. 6. P. 100115. DOI: 10.1016/j.oceram.2021.100115.
15. Jacobs P. F. Rapid prototyping & manufacturing: fundamentals of stereolithography. Dearborn: Society of Manufacturing Engineers, 1992. 434 р.
16. Krieger I. M., Dougherty T. J. A mechanism for non?Newtonian flow in suspensions of rigid spheres // Transactions of the Society of Rheology. 1959. V. 3, No. 1. P. 137 – 152. DOI: 10.1122/1.548848
17. Einstein A. Berichtigung zu meiner Arbeit: “Eine neue Bestimmung der Molek?ldimensionen” // Ann. Phys. 1911. V. 339. P. 591 – 592. DOI: https://doi.org/10.1002/andp.19113390313.
The article can be purchased
electronic!
PDF format
500 руб
DOI: 10.14489/glc.2022.10.pp.003-010
Article type:
Research Article
Make a request