Ceramics was obtained from the mixture of ZnO, SnO2 and TiO2 nanopowders by the method of solid-state sintering at 1123 K and 1443 K. The indicated nanopowders are used as components in arc dampers and for dispersion-strengthening in silver-based electrical contact materials. The phase formation and microstructure of the obtained material were studied by the methods of scanning electron microscopy, energy dispersive microanalysis and X-ray phase analysis. It is shown that at a sintering temperature of 1123 K a dispersed structure was formed, with the size of the Zn2TiO4 and ZnO phases being 0.5 – 1.0 µm. The solid phase reactions in the system ZnO/TiO2 at Тsint = 1123 K resulted in the formation of two-phase ceramics ZnO/Zn2TiO4 with the residual amounts of the phases of zinc and tin oxides. At Тsint = 1443 K there occurred the grain growth, Zn2SnO4 became the predominant phase and there remained a certain amount of the zinc and tin oxide phases.
Galina M. Zeer – PhD tech. Sciences, Associate Professor, Department of Materials Science and Materials Processing Technology, Polytechnic Institute, Siberian Federal University, Krasnoyarsk, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
Elena G. Zelenkova – PhD tech. Sciences, Associate Professor, DEPARTMENT of Design and technological support of machine-building industries, Polytechnic Institute, Siberian Federal University, Krasnoyarsk, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
Aleksandr A. Shubin – PhD chem. Sciences Associate Professor, Department of Physical and Inorganic Chemistry, Institute of Non-Ferrous Metals and Materials Science, Siberian Federal University, Krasnoyarsk, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
Artur K. Abkaryan – PhD tech. Sciences, Associate Professor, Department of Radio Electronic Systems, Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
Vasiliy V. Beletsky – PhD chem. Sciences Associate Professor, Department of Physical and Inorganic Chemistry, Institute of Non-Ferrous Metals and Materials Science, Siberian Federal University, Krasnoyarsk, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
1. Sheikh M., Pazirofteh M., Dehghani M., et al. Application of ZnO nanostructures in ceramic and polymeric membranes for water and wastewater technologies: A review // Chemical Engineering Journal. 2020. V. 391, No. 123475.
2. Bueno P. R., Varela J. A., Longo E. SnO2, ZnO and related polycrystalline compound semiconductors: An overview and review on the voltage-dependent re-sistance (non-ohmic) feature (Review) // Journal of the European Ceramic Society. 2008. V. 28, Is. 3. P. 505 – 529.
3. Bueno P. R., Varela J. A. Electronic Ceramics Based on Polycrystalline SnO2, TiO2 and (Snx Ti1–x)O2 Solid Solution // Materials Research. 2006. V. 9, No. 3. P. 293 – 300.
4. Зеер Г. М., Зеленкова Е. Г., Белецкий В. В. и др. Микроструктура и свойства электроконтактного материала Cu-(ZnO/TiO2) // Журнал технической физики. 2015. Т. 85, Вып. 12. С. 88 – 92.
5. Зеер Г. М., Зеленкова Е. Г., Сидорак А. В. и др. Электроконтактный материал на основе серебра, дисперсно-упроченный оксидами цинка, олова и титана // Журнал технической физики. 2020. Т. 90, № 8. С. 1303 – 1310.
6. Holm H. Electric Contacts. Berlin: Springer-Verlang, 2010. 482 р.
7. Wu C. P., Yi D. Q., Li J. L. R., et al. Investigation on microstructure and performance of Ag/ZnO contact material // J. Alloys and Compounds. 2008. V. 457, Is. 1-2. P. 565 – 570.
8. Guzm?n D., Mu?oz P., Aguilar C., et al. Synthesis of Ag–ZnO powders by means of a mechanochemical process // Appl. Phys. A. Mat. Sci. Proc. 2014. V. 117, Is. 2. P. 871 – 875.
9. ?osovi? V., Talijan N., ?ivkovi? D., et al. Comparison of properties of silver-metal oxide electrical contact materials // Journal of Mining and Metallurgy. Sec. B. Metallurgy. 2012, V. 48, No. 1. P. 131 – 141.
10. Kr?tzschmar A., Herbst R., M?tzel T., et all. Basic Investigations on the Behavior of Advanced Ag/SnO2 Materials for Contactor Applications // Proc. of the 56th IEEE Holm Conf. on Electrical Contacts. Charleston, SC, USA, 4 – 7 Oct. 2010. Charleston, 2010. P. 127 – 133.
11. Qiao X., Shen Q., Zhang L., et al. A Novel Method for the Preparation of Ag/SnO2 Electrical Contact Materials // Rare Metal Materials and Engineering. 2014. V. 43, Is. 11. P. 2614 – 2618.
12. Zhu Y., Wang J., An L., et al. Preparation and study on nano-Ag/SnO2 electrical contact material doped rare earth element // Rare Metal Materials and Engineering. 2014. V. 43, No. 7. P. 1566 – 1570.
13. Yancai Z., Jingqin W., Liqiang A., et al. Study on Ag/SnO2/TiO2 electrical contact materials prepared by liq-uid phase in-situ chemical route // Advanced Materials Reserch. 2014. V. 936. P. 486 – 490.
14. Schatt W., Wieters K.-P., Kieback B. Pulvermetallurgie. Technologien und Werkstoffe. Dresden–Berlin–Heidelberg: Springer-Verlag, 2007. 547 p.
15. Jiang Y., Liu S. H., Chen J. L., et al. Preparation of rodlike SnO2 powder and its application in Ag–SnO2 electrical contact materials // Materials Research Innova-tions. 2015. V. 19, Is. S4. P. 152 – 156.
16. Rohini R., Pugazhendhi Sugumaran C. Enhancement of Electro-Thermal Characteristics of Micro/Nano ZnO Based Surge Arrester // Journal of Electrical Engineer-ing and Technology. 2021. V. 16, No. 1. P. 469 – 481.
17. Zeer G. M., Zelenkova E. G., Nikolaeva N. S., et al. Microstructure and Phase Composition of the Two-Phase Ceramic Synthesized from Titanium Oxide and Zinc Oxide // Science of Sintering. 2018. V. 50, Is. 2. P. 173 – 181.
18. Николаева Н. С., Иванов В. В., Шубин А. А. Синтез высокодисперсных форм оксида цинка: химическое осаждение и термолиз // Журнал Сибирского федерального университета. Сер. Химия, 2010. Т. 3, № 2. С. 153 – 173.
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