Hollow glass microspheres from sodium borosilicate glass were obtained by high-temperature method, the composition of mass%: 10 Na2O; 8 CaO; 0,3 MgO; 0,2 Al2O3; 9 B2O3; 0,5 SO3; 72 SiO2. It is established that the maximum yield of microspheres up to 87% is observed when using a propane-air torch with the characteristics: the air/propane ratio is 1,3; the maximum temperature on the torch axis is 1900 °C; the opening angle is ~15°; the flow rate of the transporting gas is 0,2 g/s. The hollow glass microspheres obtained in this mode are characterized by a median diameter of 60 microns, an average wall thickness of 1,3 microns, a bulk density of 260 kg/m3 and a calculated strength of 50 MPa.
Valentin V. Shekhovtsov – Candidate of Technical Sciences, Associate Professor of the Department of Applied Mechanics and Materials Science, Tomsk State University of Architecture and Civil Engineering (TSASU), Tomsk, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it..
Olga V. Kazmina – Doctor of Technical Sciences, Professor of the N. M. Kizhner Research Center, Engineering School of New Production Technologies (ISNPT), Tomsk, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.
Nelly K. Skripnikova – Doctor of Technical Sciences, Professor of the Department of Applied Mechanics and Materials Science, Tomsk State University of Architecture and Civil Engineering (TSASU), Tomsk, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.
Kirill V. Skirdin – Postgraduate student, Tomsk Polytechnic University, N. M. Kizhner Research Center, Engineering School of New Production Technologies (ISNPT), Tomsk, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.
Roman Yu. Bakshansky – Master's Student, Tomsk State University of Architecture and Civil Engineering (TSASU), Tomsk, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.
Arina V. Belyaeva – Master's student, Tomsk Polytechnic University, N. M. Kizhner Research Center, Engineering School of New Production Technologies (ISNPT), Tomsk, Russia. E-mail: This email address is being protected from spambots. You need JavaScript enabled to view it.
1. Karasu B., Demirel ?., ?ztuvan A., Burak ?. Glass microspheres // El-cezer? journal of science and engineering. 2019. V. 6, Nо. 3. P. 613 – 641.
2. Zhang Yl., Zang Cg., Jiao Qj., She-li Yf. Heat-insulating materials with high-temperature resistance through binding hollow glass microspheres with vinyl-functionalized polyborosiloxane // Journal of materials science. 2020. V. 55. P. 14264 – 14279.
3. Wu C., Wang W., Ji H. Preparation and properties of TiO2-coated hollow glass microspheres as thermal insulation materials for energy-saving buildings // Transactions of Tianjin university. 2020. V. 26. P. 283 – 291.
4. Gogoi R., Kumar N., Mireja S., et al. Effect of hollow glass microspheres on the morphology, rheology and crystallinity of short bamboo fiber-reinforced hybrid polypropylene composite // The Journal of the Minerals, Metals & Materials Society (TMS). 2019. V. 71. P. 548 – 558.
5. Awais H., Nawab Y., Anjang A., et al. Mechanical properties of continuous natural fibres (jute, hemp, flax) reinforced polypropylene composites modified with hollow glass microspheres // Fibers and Polymers. 2020. V. 21. P. 2076 – 2083.
6. Zheng J., Chen L., Wang P., et al. A novel cryogenic insulation system of hollow glass microspheres and self-evaporation vapor-cooled shield for liquid hydrogen storage // Frontiers in Energy. 2020. V. 14. P. 570 – 577.
7. Vaz C. M. P., Porto L. F., D?Alkaine C. I., et al. Design and characterization of a pneumatic micro glass beads matrix sensor for soil water potential threshold control in irrigation management // Irrigation Science. 2022. V. 40. P. 397 – 405.
8. Атрощенко Г. Н., Савинков В. И., Палеари А. и др. Стеклообразные микросферы для ядерной меди-цины с повышенным содержанием оксида иттрия // Стекло и керамика. 2012. № 2. С. 3 – 7.[Atroshchenko G. N., Savinkov V. I., Paleari A., et al. Glassy microspheres with elevated yttrium oxide content for nuclear medicine // Glass Ceram. 2012. V. 69, No. 1–2. P. 39 – 43.]
9. Kurilova I., Bendet A., Fung E. K., et al. Radiation segmentectomy of hepatic metastases with Y-90 glass microspheres // Abdominal Radiology. 2021. V. 46. P. 3428 – 3436.
10. Ebbers S. C., van Roekel C., Braat M. N. G. J. A., et al. Dose–response relationship after yttrium-90-radioembolization with glass microspheres in patients with neuroendocrine tumor liver metastases // European Journal of Nuclear Medicine and Molecular Imaging. 2022. V. 49. P. 1700 – 1710.
11. Feng Y. C., Ma C. Y., Deng J. G., et al. A comprehensive review of ultralow-weight proppant technology // Petroleum Science. 2021. V. 18. P. 807 – 826.
12. Srivastava T., Katari N. K., Krishna M. S., et al. Studies on hollow glass microsphere reinforced silicone matrix composite for use in fast curing low density thermal insulation coating applications // Fibers and Polymers. 2022. V. 23. P. 175 – 183.
13. Бобкова Н. М., Трусова Е. Е., Савчин В. В. и др. Получение полых стеклянных микросфер и их применение в производстве водно-дисперсионных лакокрасочных материалов // Стекло и керамика. 2019. № 11. С. 3 – 7.[Bobkova N. M., Trusova E. E., Savchin V. V., et al. Obtaining hollow glass microspheres and their use in the production of water-dispersion coatings // Glass Ceram. 2020. V. 76, No. 11–12. P. 401 – 405.]
14. Nuzulia N. A., Islam T., Saputra A., et al. Developing highly porous glass microspheres via a single-stage flame spheroidisation process // Journal of Physics: Conference Series. 2022. V. 2243, No. 1.
15. Suzuki S., Sasaki K., Nakatsuka N., et al. A study of fine particle spheroidization process by elevated-pressure pure oxygen flame // ASME/JSME 2011. 8th Thermal Engineering Joint Conference. 2011.
16. Gupta D., Hossain K. M. Z., Ahmed I., et al. Flame-spheroidized phosphate-based glass particles with improved characteristics for applications in mesenchymal stem cell culture therapy and tissue engineering // ACS Applied Materials and Interfaces. 2018. V. 10, No. 31. P. 25972 – 25982.
17. Hossain K. M. Z., Patel U., Kennedy A. R., et al. Porous calcium phosphate glass microspheres for orthobiologic applications // Acta Biomaterialia. 2018. V. 72. P. 396 – 406.
18. Hongyun J., Liang X., Shuen H. Preparation of spherical silica powder by oxygen–acetylene flame spheroidization process // Journal of Materials Processing Technology. 2010. V. 210, No. 1. P. 81 – 84.
19. Poirier T., Labrador N., Gamarra M., et al. Smoothing iron oxide-based glass particles with an oxyacetylenic flame // High Temperature Material Processes. 2005. V. 2005, No. 4. P. 509 – 520.
20. Bortot M. B., Prastalo S., Prado M. Production and characterization of glass microspheres for hepatic cancer treatment // Procedia Materials Science. 2012. V. 1. P. 351 – 358.
21. Lee M. Y., Tan J., Heng J. Y. Y., Cheeseman C. A comparative study of production of glass microspheres by using thermal process // IOP Conference Series: Materi-als Science and Engineering. 2017. V. 205, No. 1.
22. Пат. 2319673 РФ, МПК 51 C03B 19/10. Устройство для изготовления стеклянных микрошариков и микросфер / А. Н. Трофимов, Т. Л. Басаргин, Н. Н. Трофимов и др. Заявитель и патентообладатель ОАО «Научно-производственное объединение «Стекло- пластик». Заявка № 2006124631/03; заявл. 11.07.2006; опубл. 20.03.2008, Бюл. № 8. 7 с.
23. Пат. 2059574 РФ, МПК 6 C 03 B 19/10. Способ получения полых стеклянных микросфер / В. В. Будов, А. В. Косяков, В. Г. Касыгин и др. Заявка № 5041215/33; заявл. 07.05.1992; опубл. 10.05.1996. 9 с.
24. Пат. 2278078 РФ, МПК 51 C 03 B 19/10. Устройство для изготовления стеклянных микрошариков / А. Н. Трофимов, Т. Л. Басаргин, Н. Н. Трофимов и др. Заявитель и патентообладатель ОАО «Научно-производственное объединение «Стекло-пластик». За-явка № 2005100637/03; заявл. 14.01.2005; опубл. 20.06.2006, Бюл. № 17. 7 с.
25. Бобкова Н. М., Савчин В. В., Трусова Е. Е., Павлюкевич Ю. Г. Реологические основы получения полых стеклянных микросфер на основе щелочно-боросиликатных систем // Стекло и керамика. 2018. № 1. С. 3 – 7.[Bobkova N. M., Savchin V. V., Trusova E. E., Pavlyukevich Yu. G. Rheological foundations for hollow glass microspheres production in alkali-borosilicate systems // Glass Сeram. 2020. V. 75, No. 1–2. P. 1 – 4.]
26. Елкина А. В., Парамонова А. М., Власова С. Г. Исследование физико-химических свойств боросиликатных стекол для изготовления стекловолокнистых материалов // Физика и химия стекла. 2018. Т. 44, № 3. С. 290 – 293.
27. Арбузов В. А., Арбузов Э. В., Дубнищев Ю. Н. и др. Восстановление методами гильберт-оптики поля температуры при горении предварительно перемешанных пропановоздушных смесей // Автометрия. 2020. Т. 56, № 1. С. 74 – 82.
28. Бажайкин А. Н., Баев В. К., Гуляев И. П. Измерение температуры пламени при горении встречных струй // Вестник Югорского государственного университета. 2015. № 2(37). С. 7 – 13.
29. Магунов А. Н., Пыльнев М. А., Лапшинов Б. А. Спектральная пирометрия объектов с неизвестной излучательной способностью в области температур 400 – 1200 К // Приборы и техника эксперимента. 2014. № 1. С. 128.
The article can be purchased
electronic!
PDF format
500
DOI: 10.14489/glc.2023.04.pp.003-011
Article type:
Research Article
Make a request
