The phase composition of the powder synthesized from aqueous solutions of sodium silicate Na2SiO3 and iron sulfate FeSO4 at the molar ratio Fe/Si = 2 according to X-ray diffraction (XRD) data included hydrated sodium iron sulfate Na2Fe(SO4)2·4H2O and X-ray amorphous product with the composition represented by hydrated iron and silicon oxides. The phase composition of the powder obtained by 4-times washing of the synthesized powder in distilled water included only an X-ray amorphous product.
After firing in air in the range of 400…1200 ?C, hematite Fe2O3 and cristobalite SiO2 were found in powder samples and ceramics based on these powders. After firing at 900 ?C under graphite powder the phase composition of ceramic samples included magnetite Fe3O4, laihunite Fe4,74(SiO4)3 and fyalite Fe2SiO4. The powder prepared from the product isolated from the mother liquor included hydrated sodium iron sulfate Na2Fe(SO4)2·4H2O and sodium iron sulfate hydroxide hydrate (metasideronatrite) Na4Fe2(SO4)4(OH)2·3H2O. After heat treatment at 400 ?C, sodium iron sulfate Na3Fe(SO4)3 was the predominant phase in this powder. Powders obtained as a result of the interaction of aqueous solutions of sodium silicate and iron sulfate can be used to manufacture of high-temperature dyes and materials with magnetic properties; to create analogues of lunar or Martian regolith; and also, be of interest for research related to the development of functional (cathode) materials for Na-ion batteries.
Tatiana V. Safronova – PhD (Engineering), senior researcher, Department of Chemistry, Materials Science Department, Lomonosov Moscow State University, Moscow, Russia
Muslim R. Akhmedov – assistant, Faculty of Space Research, Lomonosov Moscow State University, Moscow, Russia
Kirill S. Zakharov – student, Faculty of Materials Sciences, Lomonosov Moscow State University, Moscow, Russia
Egor A. Motorin – student, Faculty of Materials Sciences, Lomonosov Moscow State University, Moscow, Russia
Tatiana B. Shatalova – PhD (Chemistry), Associate Professor, Department of Chemistry, Materials Science Department, Lomonosov Moscow State University, Moscow, Russia
Yaroslav Yu. Filippov – PhD (Chemistry), senior researcher, research Institute of Mechanics, Materials Science Department, Lomonosov Moscow State University, Moscow, Russia
Albina M. Murashko – student, Faculty of Materials Sciences, Lomonosov Moscow State University, Moscow, Russia
Tatiana V. Filippova – engineer, Department of Chemistry, Lomonosov Moscow State University, Moscow, Russia
Olga V. Boitsova – senior researcher, Faculty of Chemistry, Lomonosov Moscow State University, Moscow, Russia
Irina V. Kolesnik – Associate Professor, Faculty of Chemistry, Faculty of Materials Sciences, Lomonosov Moscow State University, Moscow, Russia
Olga T. Gavlina – PhD (Chemistry), senior researcher, Department of Chemistry, Lomonosov Moscow State University, Moscow, Russia
Pavel E. Kazin – Professor, Faculty of Chemistry, Lomonosov Moscow State University, Moscow, Russia
1. Добыча космических ресурсов: оценка возможностей и перспектив добычи ресурсов вне Земли / под ред. И. Н. Мысляевой, М. Р. Ахмедова. Москва: КУРС, 2022. 192 с.
2. Phinney W., Criswell D. Lunar resources and their utilization / 3rd Conference on Space Manufacturing Facilities. 09 May 1977 – 12 May 1977. Princeton, NJ, U.S.A. 1977. 537. P. 1 – 10. URL: https://doi.org/10.2514/6.1977-537
3. Burns R. G., Fisher D. S. Iron?sulfur mineralogy of Mars: Magmatic evolution and chemical weathering products // Journal of Geophysical Research: Solid Earth. 1990. V. 95, No. B9. P. 14415 – 14421. URL: https://doi.org/10.1029/JB095iB09p14415
4. Bell III J. F., McSween Jr. H. Y., Crisp J. A., et al. Mineralogic and compositional properties of martian soil and dust: results from Mars Pathfinder // Journal of Geophysical Research: Planets. 2000. V. 105, No. E1. P. 1721 – 1755. URL: https://doi.org/10.1029/1999JE001060
5. Taylor L. A., Pieters C. M., Britt D. Evaluations of lunar regolith simulants // Planetary and Space Science. 2016. V. 126. P. 1 – 7. URL: https://doi.org/10.1016/j.pss.2016.04.005
6. Ramkissoon N. K., Pearson V. K., Schwenzer S. P., et al. New simulants for martian regolith: Controlling iron variability // Planetary and Space Science. – 2019. V. 179. P. 104722. URL: https://doi.org/10.1016/j.pss.2019.104722
7. Papike J. J., Simon S. B., Laul J. C. The lunar regolith: Chemistry, mineralogy, and petrology // Reviews of Geophysics. 1982. V. 20, No. 4. P. 761 – 826. URL: https://doi.org/10.1029/RG020i004p00761
8. Papike J. J., Karner J. M., Shearer C. K., Burger P. V. Silicate mineralogy of martian meteorites // Geochimica et Cosmochimica Acta. 2009. V. 73, No. 24. P. 7443 – 7485. URL: https://doi.org/10.1016/j.gca.2009.09.008
9. Ананьев П. П., Гридин О. М., Плотникова А. В., Смирнова Ю. В. Технологии извлечения воды из грунтов космических природных объектов // Горный информационно-аналитический бюллетень (научно-технический журнал). 2013. No. 10. С. 272 – 277. URL: https://www.elibrary.ru/item.asp?id=20779034
10. Zhang L., Gao F., Deng T., et al. Phase equilibria in the FeO–Fe2O3–SiO2 system: Experimental measurement and thermodynamic modeling // Calphad. 2022. V. 79. P. 102459. URL: https://doi.org/10.1016/j.calphad.2022.102459
11. Паньков В. Л., Калачников А. А., Калинин В. А. Фазовая диаграмма системы FeO–SiO2 // Известия Академии наук СССР: Физика земли. 1991. № 7. С. 3 – 11.
12. Yagi T., Akaogi M., Shimomura O., et al. In situ observation of the olivine?spinel phase transformation in Fe2SiO4 using synchrotron radiation // Journal of Geophysical Research: Solid Earth. 1987. V. 92, No. B7. P. 6207 – 6213.
13. Noguchi T., Nakamura T., Misawa K., et al. Laihunite and jarosite in the Yamato 00 nakhlites: Alteration products on Mars? // J. Geophys. Res. 2009. V. 114. E10004. URL: https://doi.org/10.1029/2009JE003364
14. Kondoh S., Kitamura M., Morimoto N. Synthetic laihunite (?xFe2?3x2+Fe2x3+SiO4), an oxidation product of olivine // American Mineralogist. 1985. V. 70, No. 7–8. P. 737 – 746.
15. Wang S. The stability of laihunite – a thermodynamic analysis // Geochemistry. 1982. V. 1. P. 233 – 245. URL: https://doi.org/10.1007/BF03180332
16. DeAngelis M. T., Rondinone A. J., Pawel M. D., et al. Sol-gel synthesis of nanocrystalline fayalite (Fe2SiO4) // American Mineralogist. 2012. V. 97, No. 4. P. 653 – 656. URL: https://doi.org/10.2138/am.2012.3899
17. URL: https://doi.org/10.1007/s11837-017-2699-6
18. Chang Q., Zhang C., Liu C., et al. Facile large?scale synthesis of nanoscale fayalite, ??Fe2SiO4 // ChemistrySelect. 2017. V. 2, No. 11. P. 3356 – 3361. URL: https://doi.org/10.1002/slct.201700047
19. ICDD. International Centre for Diffraction Data; Kabekkodu S., Ed.; ICDD: Newtown Square, PA, USA, 2010; PDF-4+ 2010 (Database). URL: https://www.icdd.com/pdf-2/
20. Nakamoto K. Infrared and raman spectra of inorganic and coordination compounds, 5th ed.; Wiley: New York, NY, USA, 1986. P. 156 – 159.
21. G?nin J. M. R., Bourri? G., Trolard F., et al. Thermodynamic equilibria in aqueous suspensions of synthetic and natural Fe (II) ? Fe (III) green rusts: Occurrences of the mineral in hydromorphic soils // Environmental Science & Technology. 1998. V. 32, No. 8. P. 1058 – 1068. URL: https://doi.org/10.1021/es970547m
22. Simon L., Fran?ois M., Refait P., et al. Structure of the Fe (II–III) layered double hydroxysulphate green rust two from Rietveld analysis // Solid State Sciences. 2003. V. 5, No. 2. P. 327 – 334. URL: https://doi.org/10.1016/S1293-2558(02)00019-5
23. Musi? S., Filipovi?-Vincekovi? N., Sekovani? L. Precipitation of amorphous SiO2 particles and their properties // Brazilian journal of chemical engineering. 2011. V. 28. P. 89 – 94. URL: https://doi.org/10.1590/S0104-66322011000100011
24. Van der Giessen A. A. The structure of iron (III) oxide-hydrate gels // Journal of Inorganic and Nuclear Chemistry. 1966. V. 28, No. 10. P. 2155 – 2159. URL: https://doi.org/10.1016/0022-1902(66)80100-8
25. Welo L. A., Baudisch O. Active Iron. II. Relationships among the oxide hydrates and oxides of iron and some of their properties // Chemical Reviews. 1934. V. 15, No. 1. P. 45 – 97. URL: https://doi.org/10.1021/cr60050a002
26. Langmuir D., Whittemore D. O. Variations in the Stability of precipitated ferric oxyhydroxides // Nonequilibrium Systems in Natural Water Chemistry. 1971. American Chemical Society. Chapter 8. P. 209 – 234. URL: https://doi.org/10.1021/ba-1971-0106.ch008
27. Harman R. W. Aqueous solutions of sodium silicates. VIII. General summary and theory of constitution. Sodium silicates as colloidal electrolytes // The journal of physical chemistry. 2002. V. 32, No. 1. С. 44 – 60. URL: https://doi.org/10.1021/j150283a002
28. Barpanda P., Oyama G., Ling C. D., Yamadaet A. Krohnkite-type Na2Fe(SO4)2·2H2O as a novel 3.25 V insertion compound for Na-ion batteries // Chemistry of Materials. 2014. V. 26, No. 3. P. 1297 – 1299. URL: https://doi.org/10.1021/cm4033226
29. Salame P. H. Synthesis and electrical studies of Na3Fe(SO4)3 cathode material for sodium ion batteries // AIP Conference Proceedings. – AIP Publishing, 2019. V. 2115, No. 1. URL: https://doi.org/10.1063/1.5113459
30. Сафронова Т. В. Фазовый состав керамики на основе порошков гидроксиапатита кальция, содержащих сопутствующие продукты реакции синтеза // Стекло и керамика. 2009. №. 4. С. 21 – 24. URL: https://elibrary.ru/item.asp?id=18277090[Safronova T. V. Phase composition of ceramic based on calcium hydroxyapatite powders containing byproducts of the synthesis reaction // Glass Ceram. 2009. V. 66. P. 136 – 139. URL: https://doi.org/10.1007/s10717-009-9130-x]
31. Ali I. M., Zakaria E. S., Ibrahim M. M., El-Nag-gar I. M. Synthesis, structure, dehydration transformations and ion exchange characteristics of iron-silicate with various Si and Fe contents as mixed oxides // Polyhedron. 2008. V. 27, No. 1. P. 429 – 439. URL: https://doi.org/10.1016/j.poly.2007.09.034
32. Veneranda M., Aramendia J., Bellot-Gurlet L., et al. FTIR spectroscopic semi-quantification of iron phases: A new method to evaluate the protection ability index (PAI) of archaeological artefacts corrosion systems // Corrosion Science. 2018. V. 133. P. 68 – 77. URL: https://doi.org/10.1016/j.corsci.2018.01.016
33. Ellerbrock R., Stein M., Schaller J. Comparing amorphous silica, short-range-ordered silicates, and silicic acid species by FTIR. Scientific Reports. 2022. V. 12: 11708. P. 1 – 8. URL: https://doi.org/10.1038/s41598-022-15882-4
34. Ventruti G., Scordari F., Ventura G. D., et al. The thermal stability of sideronatrite and its decomposition products in the system Na2O–Fe2O3–SO2–H2O // Physics and Chemistry of Minerals. 2013. V. 40. P. 659 – 670. URL: https://doi.org/10.1007/s00269-013-0601-9
35. Scordari F., Ventruti G., Gualtieri A. F., Lausi A. Crystal structure of Na3Fe(SO4)3: A high-temperature product (~ 400 ?C) of sideronatrite [Na2Fe(SO4)2OH·3H2O] // American Mineralogist. 2011. V. 96, No. 7. P. 1107 – 1111. URL: https://doi.org/10.2138/am.2011.3783
36. Bol'shakov K. A., Fedorov P. I., Il'ina N. I., Zh. Neorg. Khim., 8 [11] 2577 – 2579 (1963); Russ. J. Inorg. Chem. (Engl. Transl.), 8 [11] 1350 – 1352 (1963).
37. Wu P., Eriksson G., Pelton A. D., Blander M. Prediction of the thermodynamic properties and phase diagrams of silicate systems–evaluation of the FeO–MgO–SiO2 system // ISIJ international. 1993. V. 33, No. 1. P. 26 – 35. URL: https://doi.org/10.2355/isijinternational.33.26
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