The processes of powder production of CeO2 by reverse deposition are investigated. The CeO2 content in the resulting products is 99.2 % by weight. The main phase is cerium dioxide with a cubic lattice. The average particle size of the powder is ?42 microns, and the specific surface area is ?38.6 m2/g. A mass loss of 18 % occurs as a result of heating the material from 50 to 1200 °C. This mass loss is accompanied by endothermic effects with peaks on the DTA curve at temperatures of 144, 280 and 374 °C. The possibility of upgrading the properties of the resulting powder, in particular morphology, and determining the area of the most suitable application may become the topic of further research.
Diana S. Artyugina – senior laboratory assistant, Baikov Institute of Metallurgy and Materials Science Russian Academy of Sciences, Moscow, Russia
Yulia O. Leonova – junior research assistant, Baikov Institute of Metallurgy and Materials Science Russian Academy of Sciences, Moscow, Russia
Dinara R. Khayrutdinova – PhD of Engineering Sciences, junior research assistant, Baikov Institute of Metallurgy and Materials Science Russian Academy of Sciences, Moscow, Russia
Alexey G. Kolmakov – Corresponding Member of RAS, D.E.Sc., Head of the Laboratory, Baikov Institute of Metallurgy and Materials Science Russian Academy of Sciences, Moscow, Russia
Mikhail A. Sevostyanov – Ph.D. of Engineering Sciences, leading researcher, Baikov Institute of Metallurgy and Materials Science Russian Academy of Sciences, Moscow, Russia
Anton S. Lysenkov – Ph.D. of Engineering Sciences, senior researcher, Baikov Institute of Metallurgy and Materials Science Russian Academy of Sciences, Moscow, Russia
Aleksander I. Ogarkov – junior research assistant, Baikov Institute of Metallurgy and Materials Science Russian Academy of Sciences, Moscow, Russia
Artem A. Ashmarin – Ph.D. of Engineering Sciences, leading researcher, Baikov Institute of Metallurgy and Materials Science Russian Academy of Sciences, Moscow, Russia
Anatoliy A. Konovalov – Ph.D. of Chemical Sciences, leading researcher, Baikov Institute of Metallurgy and Materials Science Russian Academy of Sciences, Moscow, Russia
Vladimir G. Leontiev – Ph.D. in Physics and Mathematics, leading researcher, Baikov Institute of Metallurgy and Materials Science Russian Academy of Sciences, Moscow, Russia
1. Handbook of ferroalloys: theory and technology / ed. M. Gasik. Butterworth-Heinemann, 2013.
2. Meskin P. E., Baranchikov A. E., Ivanov V. K., et al. Synthesis of nanodisperse Co3O4 powders under hydrothermal conditions with concurrent ultrasonic treatment // Doklady Chemistry. 2003. V. 389, No. 1. P. 62–63.
3. Plakhova T. V., Romanchuk A. Yu., Yakunin S. N., et al. Solubility of nanocrystalline cerium dioxide: Experimental data and thermodynamic modeling // The Journal of Physical Chemistry C. 2016. V.120, No. 39. P. 22615 – 22626. DOI: 10.1021/acs.jpcc.6b05650
4. Baranchikov A. E., Polezhaeva O. S., Ivanov V. K., Tretyakov Y. D. Lattice expansion and oxygen non-stoichiometry of nanocrystalline ceria // CrystEngComm. 2010. V. 12, No. 11. P. 3531 – 3533.
5. Щербаков А. Б., Иванова О. С., Спивак Н. Я. и др. Синтез и биомедицинские применения нанодисперсного диоксида церия. Томск: Издательский Дом Томского государственного университета, 2016. 474 с.
6. Иванов В. К., Полежаева О. С., Третьяков Ю. Д. Нанокристаллический диоксид церия: синтез, структурно-чувствительные свойства и перспективные области применения // Российский химический журнал (Ж. Рос. хим. об-ва им. Д. И. Менделеева). 2009. Т. 53, № 2. С. 56 – 67.
7. Shcherbakov A. B., Ivanov V. K., Zholobak N. M., et al. Nanocrystalline ceria based materials – perspectives for biomedical application // Biophysics. 2011. V. 56, No. 6. P. 987 – 1004.
8. Popov A., Popova N., Ermakov A., et al. Intracellular Delivery of Antioxidant CeO2 Nanoparticles via Polyelectrolyte Microcapsules // ACS Biomaterials Science & Engineering. 2018. V. 4, No. 7. P. 2453 – 2462. DOI: 10.1021/acsbiomaterials.8b00489
9. Колесников И. В., Щербаков А. Б., Козлова Т. О. и др. Сравнительный анализ солнцезащитных характеристик нанокристаллического диоксида церия // Журнал неорганической химии. 2020. Т. 65, № 7. С. 872 – 879.
10. Li R., Yabe S., Yamashita M., et al. UV-shielding properties of zinc oxide-doped ceria fine powders derived via soft solution chemical routes // Materials Chemistry and Physics. 2002. V. 75, No. 1 – 3. P. 39 – 44.
11. Медведева С. А., Либерман Е. Ю. Особенности синтеза нанодисперсного диоксида церия // Наука и современность. 2016. № 49. С. 112 – 116.
12. Ультрадисперсные и наноразмерные порошки: создание, строение, производство и применение / под ред. академика В. М. Бузника. Томск: Изд-во НТЛ, 2009. 192 с.
13. Li F., Yu X., Pan Hongjun, et al. Synthesis of MO2 (M = Si, Ce, Sn) nanoparticles by solid-state reactions at ambient temperature // Solid State Sciences. 2000. V. 2, No. 8. P. 767 – 772.
14. Буйновский А. С., Жуков А. С., Малиновская Т. Д. и др. Синтез дисперсных металлооксидных материалов. Кн. 1. Плазмохимический метод получения оксидов иттрия и церия / отв. ред. Т. Д. Малиновская. Томск: Изд-во НТЛ, 2014. 140 с.
15. Антипов В. И., Галахов А. В., Виноградов Л. В. и др. Трансформационно-упрочненная ZrO2–CeO2 керамика на основе порошков, синтезированных методом ультразвукового распылительного пиролиза // Перспективные материалы. 2011. № 1. C. 53 – 58.
16. Pujar M. S., Hunagund S., Baretto D. A., et al. Synthesis of cerium-oxide NPs and their surface morphology effect on biological activities // Bulletin of Materials Science. 2020. V. 43, No. 1. P. 24.
17. Иванов В. К., Шариков Ф. Ю., Полежаева О. С. Формирование нанокристаллического диоксида церия из водно-спиртовых растворов нитрата церия (III) // Доклады академии наук. 2006. Т. 411, № 4. C. 485 – 487.
18. Леонтьева О. Н., Трегубова И. В., Алымов М. И. Синтез ультрадисперсных порошков железа методом гетерофазного взаимодействия // Физика и химия обработки материалов. 1993. № 5. С. 156 – 159.
19. Panasyuk G. P., Kozerozhets I. V., Semenov E. A., et. al. A new method for producing nanosized ?-Al2O3 powder // Journal of Inorganic Chemistry. 2018. V. 63, No. 10. P. 1286 – 1291.
20. Leonova Y. O., Sevostyanov M. A., Mezentsev D. O., et al. Effect of the synthesis temperature on the phase composition of Al2O3 // Journal of Physics: Conference Series. IOP Publishing, 2021. V. 1942, No. 1. P. 012052.
21. Farahmandjou M., Zarinkamar M., Firoozabadi T. Synthesis of cerium oxide (CeO2) nanoparticles using simple CO-precipitation method // Revista Mexicana de Fisica. 2016. V. 62, No. 5. P. 496 – 499.
22.Latha P., Prakash K., Karuthapandian S. Effective photodegradation of CR & MO dyes by morphologically controlled cerium oxide nanocubes under visible light illumination // Optik. 2018. V. 154. P. 242 – 250.
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