The aluminoborosilicate glass of basic composition was tested for the perlite-containing materials syntheses. The influence of the proportion of perlite filter powder in the initial mixture on the composition, structural features and individual physical properties of the synthesized materials was studied. A conclusion has been formulated regarding the conditions for implementing the vitrification process in a melt based on aluminosilicate glass of the selected composition of perlite-containing radioactive pulps in industrial installations.
Viacheslav E. Eremyashev – leading researcher, Laboratory of Experimental Mineralogy and Mineral Physics, South Ural Federal Research Center of Mineralogy and Geoecology of the Ural Branch of the Russian Academy of Sciences (SU FSC MG UB RAS), Miass, Russia
Galina G. Korinevskaya – junior researcher, Laboratory of Experimental Mineralogy and Mineral Physics, South Ural Federal Research Center of Mineralogy and Geoecology of the Ural Branch of the Russian Academy of Sciences (SU FSC MG UB RAS), Miass, Russia
Dmitry E. Zhivulin – junior researcher, Laboratory of Experimental Mineralogy and Mineral Physics, South Ural Federal Research Center of Mineralogy and Geoecology of the Ural Branch of the Russian Academy of Sciences (SU FSC MG UB RAS), Miass, Russia; South Ural State University (National Research University) Department of Scientific and Innovation Activities, SUSU, Chelyabinsk, Russia
Mikhail A. Rassomakhin – junior researcher, Laboratory of Experimental Mineralogy and Mineral Physics, South Ural Federal Research Center of Mineralogy and Geoecology of the Ural Branch of the Russian Academy of Sciences (SU FSC MG UB RAS), Miass, Russia
1. Бураков Б. Е., Похитонов Ю. А., Рязанцев В. И. и др. Определение массы и состава осадков, образующихся при растворении облученного оксидного топлива реактора ВВЭР // Радиохимия. 2010. Т. 52, № 4. С. 342 – 345.
2. НП-019–15. Сбор, переработка, хранение и кондиционирование жидких радиоактивных отходов. Требования безопасности: НП-019–15: утв. Приказом Федеральной службы Ростехнадзора от 27.07.2015. № 242.
3. Козлов М. Б., Ремизов К. В., Мартынов Е. А. и др. Модификация состава алюмофосфатных стекол с имитаторами ВАО для повышения их устойчивости. 1. Влияние модификаторов на вязкость и кристаллизационную способность расплавов // Вопросы радиационной безопасности. 2019. № 1. С. 3 – 15.
4. Ojovan M. I. Vitrification as a key solution for immobilisation within nuclear waste management // Arabian Journal for Science and Engineering. 2024. V. 50. P. 3253 – 3261. URL: https://doi.org/10.1007/s13369-024-09292-z
5. Eremyashev V. E., Osipov A. A., Korinevskaya G. G., Zhivulin D. E. Structural features and properties of multicomponent sodium-cerium/rubidium alumoborosilicate model matrix glasses of basis composition // J. Struct Chem. 2024. V. 65. P. 725 – 739. URL: https://doi.org/10.1134/S0022476624040097
6. Shaidullin S. M., Chesnokova A. Y., Kozlov P. V., et al. Study of the properties of low-melting borosilicate glasses developed for a removable small-sized melter designed by Mayak Production Association using the simplex planning method // Glass Phys Chem. 2024. V. 50. P. 127 – 138. URL: https://doi.org/10.1134/S1087659623601235
7. Kaspar T. C., Ryan J. V., Pantano C. G., et al. Physical and optical properties of the international simple glass // npj Materials Degradation. 2019. V. 3, No. 1. P. 15. URL: https://doi.org/10.1038/s41529-019-0069-2
8. Lu X., Reiser J. T., Parruzot B., et al. Effects of Al:Si and (Al+Na):Si ratios on the properties of the international simple glass, part ii: structure // Journal of the American Ceramic Society. 2020. No. 104(1). P. 183 – 207. DOI: 10.1111/jace.17447
9. Reiser J. T., Lu X., Parruzot B., et al. Effects of Al:Si and (Al+Na):Si ratios on the properties of the international simple glass, part i: physical properties // Journal of the American Ceramic Society. 2020. V. 104. P. 167 – 182. DOI: 10.1111/jace.17449
10. Ryan J. V., Smith N. J., Neeway J. J., et al. ISG-2: properties of the second international simple glass // npj Mater Degrad. 2023. V. 7, No. 47. URL: https://doi.org/10.1038/s41529-023-00352-7
11. Eremyashev V. E., Korinevskaya G. G., Bukalov S. S. Titanium in the structure of alkali borosilicate glasses // Glass Ceram. V. 2016, No. 72. P. 405 – 408. URL: https://doi.org/10.1007/s10717-016-9798-7
12. Eremyashev V. E., Zherebtsov D. A., Brazhnikov M. P., et al. Cerium influence on the thermal properties and structure of high-alkaline borosilicate glasses // J. Therm. Anal. Calorim. 2020. V. 139, No. 2. P. 991 – 997. DOI: 10.1007/s10973-019-08472-6
13. Еремяшев В. Е., Жеребцов Д. А., Осипова Л. М., Бражников М. В. Влияние кальция, бария и стронция на термические свойства боросиликатных стекол // Стекло и керамика. 2017. Т. 90, № 10. С. 3 – 6. [Eremyashov V. E., Zherebtsov D. A., Osipova L. M., Brazhnikov M. V. Effect of calcium, barium, and strontium on the thermal properties of borosilicate glasses // Glass Ceram. 2018. V. 747. P. 345 – 348.]
14. Wan J., Cheng J., Lu P. The coordination state of B and Al of borosilicate glass by IR spectra // J. Wuhan Univ. Technol. Mater. 2008. V. 23. P. 419 – 421. DOI: 10.1007/s11595-007-3419-9
15. El-Egili K. Infrared studies of Na2O–B2O3–SiO2 and Al2O3–Na2O–B2O3–SiO2 glasses // Physica B. 2003. V. 325. P. 340 – 348.
16. Moncke D., Tricot G., Winterstein-Beckmann A., et al. On the connectivity of borate tetrahedral in borate and borosilicate glasses // Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B. 2015. V. 56, No. 5. P. 203 – 211.
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