On the Possibility of Precision Control of Thermal Expansion Co-efficient of Transparent Lithium Aluminosilicate Glass-Ceramics

Dr. chem. Sci. V. N. SIGAEV ¹ ( e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it. ), Cand. tech. Sci. V. I. SAVINKOV ¹ , Cand. chem. G. Yu. SHAHGILDYAN ¹ , A. S. NAUMOV ¹ , Cand. chem. Sci. S. V. LOTAREV ¹ , Cand. tech. Sciences N. N. KLIMENKO ¹ , Cand. chem. Sci. N. V. GOLUBEV ¹ , Cand. physical-mat. M. Yu. PRESNYAKOV ² ; ¹ Federal State Budgetary Educational Institution of Higher Education & # 171; Russian Chemical-Technological University named after V.I. D. I. Mendeleev & # 187; (RKhTU named after D. I. Mendeleev) (Russia, Moscow)
² National Research Center & # 171; Kurchatov Institute & # 187; (Russia, Moscow)

Zanotto E. A bright future for glass-ceramics // Am. Ceram. Soc. Bull. 2010. V. 89. P. 19? 27. Bach H., Krause D. Low Thermal Expansion Glass Ceramics. 2nd ed. New York: Springer, 2005. Evans J. SO, Mary TA, Sleight AW Negative thermal expansion materials // Phys. B .: Condensed Matter. 1997. V. 241? 243. P. 311? 316. Mitra I., Alkemper J., Mueller R. et al. Optimized glass-ceramic substrate materials for EUVL applications // Emerging Lithographic Technologies VIII / International Society for Optics and Photonics. 2004. V. 5374. P. 96? 103. Efthimiopoulos I., Palles D., Richter S. et al. Femtosecond laser-induced transformations in ultra-low expansion glass: Microsctructure and local density variations by vibrational spectroscopy // J. Appl. Phys. 2018. V. 123. P. 233105 (1? 16). Sigaev V.N., Lipatiev A.S., Fedotov S.S. et al. Femtosecond laser modification of lithium-aluminosilicate glass containing antimony and transparent glass-ceramic obtained from it // Glass and Ceramics. 2019.? 10.S. 9? 13. Loshmanov AA, Sigaev VN, Khodakovskaya R. Ya et al. Small-angle neutron scattering on silica glasses containing titania // J. Appl. Crystallography. 1974. V. 7. P. 207? 210. Khodakovskaya R. Ya., Plutalov NF, Sigaev V.N. et al. Phase separation of glasses of the Li2O? Al2O3? SiO2? TiO2 system at the initial stages of sitallization, Phys. chem. glass. 1979.Vol. 5.S. 134? 140. Pat. RF 2 569 703 C1 IPC C03C 10/12. Method of obtaining optical glass / V. N. Sigaev, V. I. Savinkov, E. E. Stroganova, A. N. Ignatov. Publ. 11/27/2015. Savinkov VI, Shakhgildyan G. Yu., Naumov AS, et al. Influence of antimony oxide on the crystallization features of lithium-aluminosilicate glasses // Glass and Ceramics. 2019.? 10.S. 30? 34. Sigaev VN, Savinkov VI, Stroganova EE et al. Glass formation and crystallization of glasses of the lithium aluminum silicate system: the influence of the type of raw materials on the cooking and crystallization properties // Glass and ceramics. 2014.? 7.S. 3? 7. [Sigaev VN, Savinkov VI, Stroganova EE et al. Glass formation and crystallization of lithium-aluminum-silicate glass: effect of the form of the raw materials on the melting and crystallization properties // Glass Ceram. 2014. V. 71. P. 225? 228]. Sigaev VN, Savinkov VI, Stroganova EE et al. Glass formation and crystallization of glasses of the lithium aluminosilicate system: the effect of phosphorus, lithium and barium oxides on crystallization properties // Glass and ceramics. 2014.? 10, p. 21? 24. [Sigaev VN, Savinkov VI, Stroganova EE et al. Glass formation and crystallization of lithium-aluminum-silicate glass: Effect of phosphorus, lithium, and barium oxides on the crystallization properties // Glass Ceram. 2015. V. 71. P. 356? 359]. Khodakovskaya R. Ya. Chemistry of titanium-containing glasses and sitalls. Moscow: Chemistry, 1978.285 p.