The processes of synthesis of thialite ceramics by the method of heterogeneous deposition have been investigated. The influence of various factors (pH of the medium, the order of precipitation, the nature of TiO 2) on the phase transformations during its heat treatment has been studied. It has been established that this method makes it possible to obtain high-quality ceramic materials and, at the same time, to reduce the synthesis temperature. Tab. 1, ill. 4, bibliography: 10 titles.