The technological factors have been studied that have an intensifying effect on the processes of hardening and structure formation in the system of quartz sand - liquid glass. Optimized temperature and humidity conditions for the hardening of the compositions, the dispersion of the filler, the type and amount of the modifying additive, the quantitative ratio of the components of the raw mixture. High-silica liquid-glass composites for construction purposes with increased mechanical strength and water resistance have been developed.