Влияние отношения SiO2/Al2O3 на структуру, свойства и термическую стойкость геополимерных огнеупорных материалов

Докторант Л. ДЕМБОВСКА¹ (e-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.), д-р техн. наук И. ПУНДИЕНЕ² (e-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.), д-р техн. наук Д. БАЯРЕ¹ (e-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.), д-р техн. наук Г. БУМАНИС¹ (e-mail: Адрес электронной почты защищен от спам-ботов. Для просмотра адреса в вашем браузере должен быть включен Javascript.) ; ¹Рижский технический университет (RTU) (Латвия, г. Рига)
²Институт строительных материалов строительного факультета Вильнюсского технического универ-ситета им. Гедиминаса (VGTU) (Литва, г. Вильнюс)

Davidovitz J. Geopolymer. Chemistry and applications. Saint-Quentin: Institute Geopolymer, 2008. 592 р. Корнеев В. И., Брыков А. С. Перспективы развития общестроительных вяжущих веществ. Геополимеры и их отличительные особенности // Цемент и его применение. 2010. Mарт?апрель. C. 51 ? 55. Duxson P., Fernandez-Jimenez A., Provis J. L. et al. Geopolymer technology: the current state of the art // Journal of Materials Science. 2007. V. 42. P. 2917 ? 2933. Panagiotopoulou Ch., Kontori E., Perraki Th., Kakali G. Dissolution of aluminosilicate minerals and by-products in alkaline media // Journal of Materials Science. 2007. V. 42. P. 2967 ? 2973. Weng L., Sagoe-Crentsil K., Brown T., Song S. Effects of aluminates on the formation of geopolymers // Materials Science and Engineering. 2005. V. 117. P. 163 ? 168. Palomo ?., Alonso S., Fernandez-Jim?nez A. et al. Alkaline Activation of Fly Ashes: NMR Study of the Reaction Products // Journal of the American Ceramic Society. 2004. V. 87. P. 1141 ? 1145. Fern?ndez-Jim?nez A., Palomo A., Sobrados I., Sanz J. The role played by the reactive alumina content in the alkaline activation of fly ashes // Microporous and Mesoporous Materials. 2006. V. 91. N 1 ? 3. P. 111 ? 119. Bakharev T. Thermal behaviour of geopolymers prepared using class F fly ash and elevated temperature curing // Cement and Concrete Research. 2006. V. 36 N 6. P. 1134 ? 1147. Lyon R. E., Balaguru P. N., Foden A. et al. Fire-resistant aluminosilicate composites // Fire and Materials. 1997. V. 4. P. 67 ? 73. Tsaousi G-M., Douni I., Taxiarchou M. et al. Development of foamed Inorganic Polymeric Materials based on Perlite // IOP Conference Series: Materials Science and Engineering. 2016. V. 123. Korat L, Ducman V, Legat A, Mirti? B. Characterisation of the pore-forming process in lightweight aggregate based on silica sludge by means of X-ray micro-tomography (micro-CT) and mercury intrusion porosimetry (MIP) // Ceramics International. 2013. V. 39. N 6. P. 6997 ? 7005. Henon J., Alzina A., Absi J. et al. Porosity control of cold consolidated geomaterial foam: Temperature effect // Ceramics International. 2012. V. 38. N 1. P. 77 ? 84. Huiskes D. M. A., Keulen A., Yu Q. L., Brouwers H. J. H. Design and performance evaluation of ultra-lightweight geopolymer concrete // 19 Internationale Baustofftagung, 16 ? 18 September 2015, Weimar, Bundesrepublik Deutschland. 2015. V. 2. P. 1099 ? 1106. Pimraksa K., Chindaprasirt P., Rungchet A. et al. Lightweight geopolymer made of highly porous siliceous materials with various Na2O/Al2O3 and SiO2/Al2O3 ratios // Materials Science and Engineering. 2011. V. 528. N 21. P. 6616 ? 6623. Posi P., Teerachanwit C., Tanutong C. et al. Lightweight geopolymer concrete containing aggregate from recycle lightweight block // Materials & Design. 2013. V. 52. P. 580 ? 586. Novais R. M., Buruberri L. H., Seabra M. P. et al. Novel porous fly ash-containing geopolymers for pH buffering applications // Journal of Cleaner Production. 2016. V. 124. N 15. P. 395 ? 404. Bernal S. A., Rodr?guez E. D., de Guti?rrez R. M. et al. Mechanical and thermal characterisation of geopolymers based on silicate-activated metakaolin/slag blends // Journal of Materials Science. 2011. V. 46. P. 5477 ? 5486. Williams R. P., van Riessen A. Determination of the reactive component of fly ashes for geopolymer production using XRF and XRD // Fuel. 2010. V. 89. P. 3683 ? 3692. Rickard W. D. A., Temuujin J., van Riessen. A. Thermal analysis of geopolymer pastes synthesised fromfive fly ashes of variable composition // Journal of Non-Crystalline Solids. 2012. V. 358. N 15. P. 1830 ? 1839. Zhao Y., Ye J., Lu X. et al. Preparation of sintered foam materials by alkali-activated coal fly ash // Journal of Hazardous Materials. 2010. V. 174. N 1 ? 3. P. 108 ? 112. Kong D. L. Y., Sanjayan J. G., Sagoe-Crentsil K. Comparative performance of geopolymers made with metakaolin and fly ash after exposure to elevated temperatures // Cement and Concrete Research. 2007. V. 37. N 12. P. 1583 ? 1589. Lin T. S., Jia D. C., He P. G., Wang. M. R. Thermo-mechanical and microstructural characterisation of geopo-lymers with alpha alumina particulate filler // International Journal of Thermophysics. 2009. V. 30. P. 1568 ? 1577. Silva F. J., Thaumaturgo C. Fibre reinforcement and fracture response in geopolymeric materials // Fatigue & Fracture of Engineering Materials & Structures. 2003. V. 26. N 2. P. 167 ? 172. Kamseu E., Rizzuti A., Leonelli C., Perera D. Enhanced thermal stability in K2O-metakaolin-based geopolymer concretes by Al2O3 and SiO2 fillers addition // Journal of Materials Science. 2010. V. 45. P. 1715 ? 1724. Buchwald A., Vicent M., Kriegel R. et al. Geopolymeric binders with different fine fillers ? phase transformations at high temperatures // Applied Clay Science. 2009. V. 46. N 2. P. 190 ? 195. Duxson P., Lukey G. C., Jannie S. J., van Deventer J. S. J. Physical evolution of Na-geopolymer derived from metaka-olin up to 1000 °C // Journal of Materials Science. 2007. V. 42. N 9. P. 3044 ? 3054. Barbosa V. F. F., MacKenzie K. J. D. Synthesis and thermal behaviour of potassium sialate geopolymers // Materials Letters. 2003. V. 57. N 9 ? 10. P.1477 ? 1482. Bell J. L., Driemeyer P. E., Kriven W. M. Formation of ceramics from metakaolin-based geopolymers. Part II. K-based geopolymer // Journal of the American Ceramic Society. 2009. V. 92. N 3. P. 607 ? 615. Dembovska L., Bumanis G., Vitola L., Bajare D. Influence of fillers on the alkali activated chamotte // IOP Conf. Series: Materials Science and Engineering, 2017. Antonovi? V., ?uk?ta M., Pundien? I., Stonys R. Procedural elements in estimation of the thermal shock resistance of different types of refractory concrete based on chamotte filler // Refractories and Industrial Ceramics. 2011. V. 52. N 1. P. 70 ? 74. Benboudjema F., Guillon E., Torrenti J. Effect of interfacial transition zone and aggregates on the time-dependent behavior of mortar and concrete. 2002. URL: http://www.framcos. org/FraMCoS-5/Benboudjema.Effect.PDF. Fernandez-Jimenez A., Pastor J. Y., Mart?n A., Palomo A. High-temperature resistance in alkali-activated cement // Journal of the American Ceramic Society. 2010. V. 93. N 10. P. 3411 ? 3417. Pyatina T., Sugama T. Set controlling additive for thermal-shock-resistant cement // GRC Transactions. 2014. V. 38. P. 251 ? 257.