The formation of the equilibrium Cu (I) & harr; Cu (II) in colored optical glasses under the combined action of several factors. It is shown that the oxidation of copper increases with an increase in its total mass content, an increase in the content of carbonates in the charge, an increase in the basicity coefficient of the matrix and mainly depends on the ratio between the oxides of chromium, arsenic and copper. A coefficient for the quantitative assessment of the combined effect of chromium and arsenic oxides on the equilibrium of copper is proposed. Tab. 2, ill. 4, bibliography: 6 titles.
Colored optical glass and special glasses: Catalog / Ed. G. T. Petrovsky. - M., 1990 .-- 227 p.
Physicochemical Foundations of Optical Glass Production, Ed. L. I. Demkina. - L .: Chemistry, 1976 .-- 480 p.
Minko N.I., Influence of the oxidation-reduction potential of the charge on the processes of melting and properties of glass, Izbr. tr. - Belgorod: Publishing house of BSTU im. V.G.Shukhova, 2004. - pp. 23 - 32.
Dunn AG, Beales KJ Near Infrared Optical Absorption of Iron (II) in Sodium-Borosilicate Glasses // Phys. Chem. Glasses. - 1978. - V. 19.-N1.-P.1-4.
Artamonova M.V., Kiyan V.I., Mashir Yu. I. Evaluation of the acid-base properties of sodium aluminoborosilicate glasses // Glass Physics and Chemistry. - 1986. - T. 12. - N 6. - P. 731 - 739.
Scientific and technical foundations of glass production with a small attenuation index / Ed. L. I. Demkina. - L., 1982 .-- 340 p.
The article can be purchased
electronic!
PDF format
Not on sale
UDK 666.221:541.53
Article type:
Science for glass production
Make a request