Steklo i Keramika (Glass and Ceramics). Monthly scientific, technical and industrial journal

 

ISSN 0131-9582 (Online)

  • Continuous numbering: 1010
  • Pages: 14-18
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Heading: Science for glass production

Glasses were studied in the Al 2 O 3 - P 2 O 5 - SiO 2 suitable for producing green light filters used as traffic signal lights. The following requirements were imposed on glasses: maximum bandwidth at ? max = 500 nm, high temperature resistance and low LTEC - (41-49) * middot; 10 -7 K -1 . The dyes were transition elements, which were introduced into the charge in the form of oxides TiO 2 , V 2 O 5 , CuO, MoO 3 in the amount of 1% (mass fraction), as well as their pairs in various combinations. EPR and optical spectra were studied. It is shown that the glass composition (mass fraction,%): 55 P 2 O 5 ; 17,1 Al 2 O 3 ; 20 SiO 2 ; 1,5 La 2 O 3 ; 2 ZrO 2 ; 2.5 B 2 O 3 ; 1.5 MoO 3 ; 0.5 CuO can be recommended for use as heat-resistant green light filters. Il. 7, bibliography: 5 titles.
Averchenko O. E., Bogomolova L. D., Pushkareva G. I. Heat-resistant green glasses for light filters // Glass and ceramics. 1986. N 11. S. 13 - 14. Averchenko OE, Bogomolova LD, Pushkareva GI Thermal-shock resistant green glasses for light filters // Glass and Ceram. 1986. V. 43. No. 11. P. 491-494. Bogomolova L.D., Zhachkin V.A., Pavlushkina T.K. 2009. N 5.S. 17-22. Bogomolova LD, Zhachkin VA, Pavlushkina TK Electron paramagnetic resonance of V 4+ ions in lanthanum-aluminosilicate glasses // Glass and Ceram. 2009. V. 66. N5-6. P. 168-172. Binks JH, Duffy JA A molecular orbital treatment of the basicity of oxyanionunits // J. Non-Cryst. Solids. 1980. V. 37. P. 387-400. Bogomolova L.D., Grechko E.G., Zhachkin V.A. et al. EPR of Cu 2+ ions in glasses based on zirconium and hafnium tetrafluorides // Glass Physics and Chemistry. 1987. T. 13. N 2. S. 202 - 208. Bogomolova LD, Pavlushkina TK, Roshchina AV Some features of EPR and optical spectra of vanadium in alumino-phosphate glasses // J. Non-Cryst. Solids. 1983. V. 58. No. 1. P. 99-107.

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L. D. Bogomolova, V. A. Zhachkin, and T. K. Pavlushkina Developing of green filters based on oxide glass stained with transition elements. Steklo i keramika. 2012:85(2):14-18. (in Russ). UDK 666.1