Titanium in the structure of alkali borosilicate glasses

Dr. chem. Sci. V. E. EREMYASHEV ^1,2 ( e-mail: This email address is being protected from spambots. You need JavaScript enabled to view it. ), G. G. KORINEVSKAYA ² , Dr. S. S. BUKALOV ³ ; ¹ South Ural State University (Russia, Chelyabinsk)
² Institute of Mineralogy, Ural Branch of the Russian Academy of Sciences (Russia, Miass, Chelyabinsk Region) ³ Institute of Organoelement Compounds RAS (Russia, Moscow)

Farges F., Brown GE, Rehr JJ Coordination chemistry of Ti (IV) in silicate glasses and melts. I. XAFS study of titanium coordination in oxide model compounds // Geochirnica and Cosmochimica Acta. 1996. V. 60. N 16.P. 3023? 3038. Henderson GS, Liu X., Fleet ME A Ti L-edge absorption study of Ti-silicate glasses // Physic and Chemistry of Glasses. 2002. V. 29. P. 32? 42. Banerjee1 D., Sudarsan VK, Joseph A. et al. Role of TiO ₂ on the Physicochemical Properties of Cesium Borosilicate Glasses // Journal of the American Ceramic Society. 2010. V. 93. N 10.P. 3252? 3258. Eremashev VE, Osipov A. A, Osipova LM Study of the effect of substitution of sodium cation by cations of alkaline earth metals on the structure of borosilicate glasses // Glass and ceramics. 2011.? 7.S. 3? 7. Eremyashev VE, Osipov AA, Osipova LM Borosilicate glass structure with rare-earth-metal cations substituted for sodium cations // Glass and Ceram. 2011. V. 68. N 7? 8.P. 205? 208. Wan J., Cheng J., Lu P. The Coordination State of B and Al of Borosilicate Glass by IR Spectra // Journal of Wuhan University of Technology Mater. 2008. V. 23. N 3.P. 419? 421. Xiu T., Liu Q., Wang J. Alkali-free borosilicate glasses with wormhole-like mesopores // J. Mater. Chem. 2006. N 16.P. 4022? 4024. Furukawa T., White W. Raman spectroscopic investigation of sodium borosilicate glass structure // Journal of Materials Science. 1981. V. 16. N 10. P. 2689? 2700. Manara D., Grandjean A., Neuville DR Advances in understanding the structure of borosilicate glasses: A Raman spectroscopy study // American Mineralogist. 2009. V. 94. N 5? 6.P. 777? 784. Sokolov VO, Plotnichenko VG, Dianov EM Quatovochemical modeling of titanium centers in titanosilicate glass // Inorganic materials. 2006. T. 42.? 11, p. 1393? 1408. Eremyashev VE, Shabunina LA, Mironov AB Structural features of iron-containing borosilicate glasses // Glass and ceramics. 2013.? 11, p. 8? 12. Eremyashev VE, Shabunina LA, Mironov AB Structural Particulars of Iron-Containing Borosilicate Glasses // Glass and Ceram. 2013. V. 70. N 11? 12.P. 391? 394.